A high-quality and centimeter-level
three-dimensional (3D) nitrogen-doped
graphene (NG) nanonetwork is synthesized via a chemical vapor deposition
method to serve as a substrate and a current collector, which directly
germinates active metal oxides to act as a free-standing electrode
in lithium-ion batteries. By means of facile electrodeposition and
annealing processes, the tetragonal spinel cobalt–manganese
oxide nanosheets wrapped with polypyrrole pyrolytic carbon are in
situ hybridized with a 3D NG nanonetwork. In particular, the introduced
carbon protective layer can enhance the Li-ion storage capacity and
cycle stability of the composite electrode. The metallic synergistic
effect and rational carbonaceous hybridization jointly provide high-performance
charge storage and cycle stability. Notably, the surface-controlled
capacitive effect stands out contributing to the total charge storage
more than ever in nanostructure electrodes.