Self-assembling nanostructures of water-soluble fullerene[60]–chlorin e6 dyads: Synthesis, photophysical properties, and photodynamic activity

Recent progress in organometallic porphyrin‐based molecular materials for optical sensing, light conversion, and magnetic cooling

“…For the temperatures close to room, typical temperature dependencies are given in Figure 12 derived using the data of works. [173,174,178] The predominance of the electronic subsystem in magnetization is manifested in the absence of the MCE-C p correlation among structures of the same type, which is visible from the appearance of anomalies in the C p temperature dependencies for specific paramagnet as in the case of (AcO)GdPc or GdPc 2 [174] (Figure 12, Line 2).…”

“…In the first case, the MCE value depends not only from the spin state of a central ion but also from an electronic and chemical structure of bonded axial groups (Figure 13 created by using the works [166,167,[169][170][171][172][173]175,177,178] ), which ultimately leads to spin density delocalization or to ferromagnetic coupling with an additional spin carrier in a molecule structure. To give insight into the nature of spin distribution, they resort to comparative analysis of paramagnet UV-vis spectra or to computational calculations.…”

“…Just as no review can claim an absolute coverage of available data in the area under consideration, our review did not consider the results for some specific very important results for MPXs/MPcXs as molecular materials. We are here obliged to cite significant works on the study and the application of the porphyrin/phthalocyanine sensitizers for PDT/diagnostics, [ 180–187 ] the catalysts based on the porphyrin/phthalocyanine complexes of rhenium [ 188–191 ] and iridium [ 192,193 ] for redox reactions that are beyond the scope of our review, and the shift reagents based on REE porphyrin complexes in NMR. [ 194–196 ]…”

Learning from Nature: Bioinspired Chlorin-Based Photosensitizers Immobilized on Carbon Materials for Combined Photodynamic and Photothermal Therapy

“…Recently, in 2020, Rybkin and co-authors reported a material obtained by covalently linking chlorin e6 to fullerene, which was characterized by means of absorption spectroscopy, steady-state/time-resolved fluorescence spectroscopy, dynamic light scattering, and an assessment of its photocytotoxicity (light fluence of 23 mW/cm 2 ) against HeLa cancer cells (IC 50 = 1.17 µM) ( Table 3 , entry 2) [ 107 ]. Moreover, the authors evaluated the influence of the linker and the presence of a Zn metal ion in the chlorin core on the physical/chemical properties and photodynamic efficiency; they observed that these functionalized carbon nanomaterials act via both type I and type II mechanisms.…”

“…Moreover, the authors evaluated the influence of the linker and the presence of a Zn metal ion in the chlorin core on the physical/chemical properties and photodynamic efficiency; they observed that these functionalized carbon nanomaterials act via both type I and type II mechanisms. In this study, the authors also demonstrated that water-soluble fullerene derivatives, which were covalently linked to a hydrophobic dye, could be attractive for the creation of a highly active photosensitizer and as a platform for the synthesis of various nanoscale switch-off systems [ 107 ].…”