Self‐assembled fibrillar polyethylene crystals with tunable properties

Abstract

Due to its simple linear chain structure, crystal morphology of linear low‐density polyethylene (LLDPE) fibers can be controlled to fulfill the needs of diverse advanced applications. This study presents a simple two‐step method to produce LLDPE fibers with self‐assembled fibrillar crystals and highly oriented amorphous phase. Rather than conventional melt spinning, fibers were treated in a two‐step eco‐friendly bath without drawing after extruded fibers emerge from the spinneret. Treated fibers through the baths demonstrated lower crystallinity, but significantly higher degree of crystal orientation when compared to control fibers of traditional melt spinning. Morphological analysis revealed that a unique microstructure was formed after spinning through a two‐step eco‐friendly bath. As‐spun fibers demonstrated spherulitic morphology which can be transformed into a fibrillar structure followed by post‐drawing process. Cross sectional images of the treated LLDPE fibers produced at 400 m/min showed fibrillar PE crystals which can be more dominant upon post‐drawing. After two‐step bath treatment, produced fibers need low draw ratios to exhibit high performance. Our novel modification followed by hot drawing process can manipulate internal structure with performance of PE fibers to an outstanding level of 0.35 GPa strength and 3 GPa modulus at a production speed of 400 m/min.

Developing an in-Line method to improve mechanical and flame retardancy performance of polyethylene fiber

“…This novel approach to melt spinning system was described in the previous work. 30 In this study, zone I was adjusted to 160 cm at room temperature for the fiber travel length for all productions, and zone II was modified with flame retardant agents with different fiber travel lengths and temperatures. One of the most important aims is to manipulate the medium in terms of liquid temperature and viscosity induced drag force within the semi-molten thread line and interaction with the fibers.…”