While
structural color materials have nonfading properties and contribute
significantly to the sustainable development of pigments or dyes,
they are plagued by low color saturation and limited color tunability.
Here, we describe a new type of spherical colloidal photonic crystals
(CPCs) prepared by a droplet-based microfluidic strategy, featuring
enhanced color saturation and tunable structural colors. Methyl viologen
(MV) functionalized SiO2 colloids were synthesized and
used for the preparation of CPCs in microdroplets. Because of the
absorption of incoherently scattered light by MV, the ratio of peak-to-background
amplitude in the reflectance spectra of CPCs is increased, leading
to brilliant structural color with enhanced saturation. The lattice
plane exposure of spherical CPCs depends on the refractive index contrast
between the filling medium and SiO2 building blocks, and
this offers an alternative way to tune the structural color in a spherical
CPC. Accordingly, a dynamic optical display was constructed, providing
valuable insights to the future development of structural color-based
sensors, surface coatings, or displays.