1997
DOI: 10.1016/s0167-2991(97)81076-2
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Selectivity of active sites on oxide catalysts

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“…That is, the conversion rate of propane is about three times higher than that of propene under the same conditions. It seems that these catalysts have a preference for alkanes though the weakest bond in propene is about 40 kJ/mol weaker than the weakest bond in propane [21]. This might be because propene cannot react any other way than by deep oxidation to CO x as observed in Fig.…”
Section: Reaction Pathwaysmentioning
confidence: 93%
“…That is, the conversion rate of propane is about three times higher than that of propene under the same conditions. It seems that these catalysts have a preference for alkanes though the weakest bond in propene is about 40 kJ/mol weaker than the weakest bond in propane [21]. This might be because propene cannot react any other way than by deep oxidation to CO x as observed in Fig.…”
Section: Reaction Pathwaysmentioning
confidence: 93%