Study of X-ray-magnetic-circular-dichroism (XMCD) and XMCD in photoemission-electronmicroscopy (XMCD-PEEM) is for the first time performed on magnetic-field-assisted selfassembled quasi-one-dimensional (1D) nanochains of spherical ferrite particles, with a homogeneous particle size of about 200 nm and chain length of micrometers. Supported by theoretical analysis, the XMCD provides direct evidence for the distributions of the Fe 2+ O h , Fe 3+ T d and Fe 3+ O h cations and the preferential occupation of the dopant ions. A nonmonotonic H assist -dependence of the cation distribution is revealed, consistent with that of the saturation magnetization, while discrepant with that of the magnetic anisotropy. Unlike bulk ferrites, where the magnetism is predominantly determined by the crystal chemistry, in nanoscale ferrites the external synthetic conditions and shape effects play a nontrivial role as Submitted to 2 well. At H assist = 2500 Oe, the nanochains exhibit a high saturation-magnetization approaching the bulk value and relatively large magnetic anisotropy induced by the chain-like shape, which makes it a good candidate for magnetic 1D-nanodevices. XMCD-PEEM is performed on these nanochains, showing the precise trapping of magnetic domain walls in a single chain.Cobalt and zinc dopants are also incorporated to tailor the magnetic properties of these nanochains for future device applications serving diverse demands.