We review recent work at the interface of supramolecular chemistry and fullerene chemistry. We focus on selective fullerene functionalization, host–guest chemistry, non-covalent dyads, mechanically interlocked architectures and 2D/3D assemblies.
We review recent work at the interface of supramolecular chemistry and fullerene chemistry. We focus on selective fullerene functionalization, host–guest chemistry, non-covalent dyads, mechanically interlocked architectures and 2D/3D assemblies.
“…A mixture of equimolar amounts of P5-OTf and compound C7 (or C9) was refluxed with Pd(PPh 3 ) 4 as a catalyst in THF/H 2 O (5 : 1) to provide crude P5-[ n ]CPP-OMe, which was directly subjected to a reductive aromatization reaction without further purification in the presence of H 2 SnCl 4 to generate the desired products P5-[8]CPP and P5-[10]CPP (ref. 27 ) with a two-step yield of 26% and 25%, respectively. The structures of P5-[ n ]CPPs were confirmed by 1 H NMR, 13 C NMR and MALDI-TOF MS.…”
In this study, we synthesized and reported the heterotopic bisnanohoops P5-[8,10]CPP containing cycloparaphenyenes (CPPs) and a pillar[5]arene unit, which act not only as energy donors but also as a host...
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