Selective Sulfur Dioxide Absorption from Simulated Flue Gas Using Various Aqueous Alkali Solutions in a Polypropylene Hollow Fiber Membrane Contactor: Removal Efficiency and Use of Sulfur Dioxide

Abstract

Hollow fiber membrane contactors (HFMCs) provide a large specific surface area. Thus, their significantly reduced volume provides an advantage compared to the conventional gas–liquid contactor. In this study, the selective removal efficiency of flue gas, in which sulfur oxide (SO2) and carbon dioxide (CO2) coexist, was measured using a polypropylene (PP) HFMC with such advantages. To increase the selective removal efficiency of SO2, experiments were conducted using various alkaline absorbents. As a result, with 0.05 M ammonia solution, the removal efficiency of 95% or more was exhibited with continuous operation for 100 h or more. We confirmed that the absorbent saturated by the once-through mode was aqueous ammonium sulfate ((NH4)2SO4) solution and could be used as a fertilizer without additional processing.

Preparation of an innovative series of respiratory nano-filters using polystyrene fibrous films containing KCC-1 dendrimer and ZnO nanostructures for environmental assessment of SO2, NO2 and CO2

“…The reduction in the absorption rate of this pollutant compared to other pollutants is related to better interactions between the absorbent and other absorbed pollutants (CO 2 and SO 2 ), which are influenced by the type of functional groups, the type of interactions created, as well as the size of the absorbent pores and the size of the absorbed particles. 26 …”