Selective Reduction of Phenylacetylene with AlMgO Particles used as an Alternative Water-Reactive Generator of Hydrogen

Kozina, Anna; Iturbe, J.L.; Rivero, Ignacio A.

doi:10.1007/s10562-013-1019-1

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“…[36][37] The selective reduction of phenylacetylene was also investigated with AlMgO particles which were used as an alternative to water-reactive generator of hydrogen. 38 The partial hydrogenation of 3-hexyne was observed using low-loadings of palladium mono-and bimetallic catalysts. 39 A Hantzsch amido dihydropyridine has been used as a transfer hydrogenation reagent for α,β-unsaturated ketones.…”

Section: Introductionmentioning

confidence: 99%

Reduction of diphenylacetylene using Al powder in the presence of noble metal catalysts in water

et al. 2016

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Diphenylacetylenes can be reduced to the corresponding diphenylethanes (2) in water in excellent yield using Al powder and Pd/C at 60 °C for 3 h in a sealed tube. In addition, the complete reduction of both aromatic rings required 80 °C for 15 h with Al powder in the presence of Pt/C. However, the nature of hydrogenated product formed was found to be strongly influenced by the reaction temperature, time, volume of water and the amount of catalyst being employed.

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Section: Introductionmentioning

confidence: 99%