Synthetic Communications

2013

DOI: 10.1080/00397911.2011.589020

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Selective Reduction ofortho-Acylated β-Enaminones of Homoveratryamine and Their Cyclization to 1,2,3,4-Tetrahydroisoquinolines with β-Enaminone Moiety

Stoyanka Nikolova

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Ekaterina Kochovska

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Cited by 7 publications

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Tetrahydroisoquinolines

2018

Privileged Structures in Drug Discovery

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Tetrahydroisoquinolines

2018

Privileged Structures in Drug Discovery

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Four‐Component Synthesis of β‐Enaminone and Pyrazole through Phosphine‐Free Palladium‐Catalyzed Cascade Carbonylation

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et al. 2014

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The carbonylative domino synthesis of enaminones and pyrazoles has been performed with the NN bidentate palladium catalyst to achieve excellent selectivity. These results have confirmed that the carbonylative Sonogashira coupling of iodobenzenes with terminal alkynes is accompanied by the Michael addition of amines or phenylhydrazine in a one‐pot method, which generates the desired products. This protocol demonstrates wide substrate tolerance, including hitherto unused aromatic amines, to yield the corresponding pure aromatic β‐enaminones, which are subsequently converted into the 3‐acylindole derivatives under mild conditions.

ChemInform Abstract: Selective Reduction of ortho‐Acylated β‐Enaminones of Homoveratryamine (I) and Their Cyclization to 1,2,3,4‐Tetrahydroisoquinolines with β‐Enaminone Moiety (III).

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2013

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Selective Reduction of ortho-Acylated β-Enaminones of Homoveratryamine (I) and Their Cyclization to 1,2,3,4-Tetrahydroisoquinolines with β-Enaminone Moiety (III). -(NIKOLOVA, S.; KOCHOVSKA, E.; IVANOV*, I.; Synth. Commun. 43 (2013) 3, 326-336, http://dx.

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