Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO<sub>3</sub><sup>-</sup>-LDHs

王力耕,; 陈璐焌,; 章华隆,; 余琴,

doi:10.6023/cjoc201705017

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2020

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“…Please see the specific synthetic procedure and calculation of iodometric method in the Supplementary Materials. We have utilized ZnAl-BrO 3 − -LDHs to achieve bromination of olefins and anilines [67][68][69]. Herein, we proposed a mild and efficient KBr and ZnAl-BrO 3 − -LDHs system for selective mono-bromination of phenols.…”

Section: Introductionmentioning

confidence: 99%

Regioselective Monobromination of Phenols with KBr and ZnAl–BrO3−–Layered Double Hydroxides

et al. 2020

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The regioselective mono-bromination of phenols has been successfully developed with KBr and ZnAl–BrO3−–layered double hydroxides (abbreviated as ZnAl–BrO3−–LDHs) as brominating reagents. The para site is much favorable and the ortho site takes the priority if para site is occupied. This reaction featured with excellent regioselectivity, cheap brominating reagents, mild reaction condition, high atom economy, broad substrate scope, and provided an efficient method to synthesize bromophenols.

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Section: Introductionmentioning

confidence: 99%

Regioselective Monobromination of Phenols with KBr and ZnAl–BrO3−–Layered Double Hydroxides

et al. 2020

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Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO₃^--LDHs

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Regioselective Monobromination of Phenols with KBr and ZnAl–BrO3−–Layered Double Hydroxides

Regioselective Monobromination of Phenols with KBr and ZnAl–BrO3−–Layered Double Hydroxides

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Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO3--LDHs

Cited by 1 publication

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Regioselective Monobromination of Phenols with KBr and ZnAl–BrO3−–Layered Double Hydroxides

Regioselective Monobromination of Phenols with KBr and ZnAl–BrO3−–Layered Double Hydroxides

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Selective Oxidative Bromination of Anilines Using Potassium Bromide and ZnAl-BrO₃^--LDHs