Selective oxidation of benzyl alcohol on poly(4-(3-(pyrrol-1-yl)propionamido)-2,2,6,6-tetramethylpiperidin-1-yloxy) electrode

Yi, Jingmiao; Tang, Danyang; Song, Dandan; Wu, Xiaohua; Shen, Zhenlu; Li, Meichao

doi:10.1007/s10008-015-2843-6

Cited by 13 publications

(7 citation statements)

References 35 publications

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“…With the increasing of potential, the corresponding infrared spectra signals could be seen clearly at approximately 400 mV. The downward bands at 1646, 1629, and 1587 cm −1 were contributed to ring stretching vibration of 2,6-lutidinium cation [57]. The band at 1176 cm −1 was related to C-H in-plane bending of 2,6-lutidinium cation [58,59].…”

Section: Resultsmentioning

confidence: 99%

Electrochemical Performance of ABNO for Oxidation of Secondary Alcohols in Acetonitrile Solution

et al. 2018

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The ketones was successfully prepared from secondary alcohols using 9-azabicyclo[3.3.1]nonane-N-oxyl (ABNO) as the catalyst and 2,6-lutidine as the base in acetonitrile solution. The electrochemical activity of ABNO for oxidation of 1-phenylethanol was investigated by cyclic voltammetry, in situ Fourier transform infrared spectroscopy (FTIR) and constant current electrolysis experiments. The resulting cyclic voltammetry indicated that ABNO exhibited much higher electrochemical activity when compared with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) under the similar conditions. A reasonable reaction mechanism of the electrocatalytic oxidation of 1-phenylethanol to acetophenone was proposed. In addition, a series of secondary alcohols could be converted to the corresponding ketones at room temperature in 80–95% isolated yields.

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Section: Resultsmentioning

confidence: 99%

Electrochemical Performance of ABNO for Oxidation of Secondary Alcohols in Acetonitrile Solution

et al. 2018

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“…80 Yi and co-workers were able to synthesize the derivative monomer of pyrrole having the side chain nitroxyl radical, 4-(3-(pyrrol-1-yl) propionamido)-2,2,6,6-tetramethylpiperidin-1-yloxy (PyATEMPO). 81 Also, its polymer PPyATEMPO was efficaciously developed by cyclic voltammetry on a Pt electrode in NaClO 4 /CH 3 solution and was later characterized utilizing SEM. Cyclic voltammograms and in situ FTIR spectroscopic techniques were able to predict the electrocatalytic activity of PPyATEMPO and the underlying mechanism in the electrochemical oxidation of benzyl alcohol on PPyATEMPO electrode respectively.…”

Section: Tempo Mediated Electrocatalytic Oxidation Of Alcoholsmentioning

confidence: 99%

Review—Electrocatalytic Oxidation of Alcohols Using Chemically Modified Electrodes: A Review

Rajeev

Sharma

Mathew

et al. 2020

J. Electrochem. Soc.

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Electrocatalytic oxidation of alcohols utilizing chemically modified electrodes is considered as a green and facile method. This method is also considered as a feasible solution for a "clean" and efficient energy production, is more economic and produces less toxic and minimal waste. Electrocatalytic oxidation of alcohols is of great interest as many of its products find applications in chemical, pharmaceutical, and food industries. The major classifications of chemical modification to the electrodes for electrocatalytic oxidation of alcohols discussed in this review include conducting polymers, noble metal nanoparticles, metal oxides, or metal-oxides as nanoparticles and reduced graphene oxide-based modifications. Despite its wide range of applications and environmentally benign nature, electrocatalytic oxidation of alcohols using chemically modified electrodes is underutilized, less appreciated, and still in its infancy stages. This review aims to provide the readers with an overview in the field of electrocatalytic oxidation of alcohols by incorporating two significant applications-Electroorganic conversion of alcohols to aldehydes and their applications in alcohol-based fuel cells. Further, this also presents an outlook for gaining deeper insights for making this methodology more economic, and applicable in various synthetic organic chemistry fields.

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“…Therefore, we reason that the increased catalytic current could be attributed to the electrochemical oxidation of TEMPOH catalyzed by the base, as this process often requires a large over-potential in the absence of base. 24 The CVs of the reaction in various bases were obtained and are shown in Fig. 2c.…”

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Synthesis of p-cymene by the electrocatalytic oxidation of α-terpinene and γ-terpinene

et al. 2023

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Selective oxidation of benzyl alcohol on poly(4-(3-(pyrrol-1-yl)propionamido)-2,2,6,6-tetramethylpiperidin-1-yloxy) electrode

Cited by 13 publications

References 35 publications

Electrochemical Performance of ABNO for Oxidation of Secondary Alcohols in Acetonitrile Solution

Electrochemical Performance of ABNO for Oxidation of Secondary Alcohols in Acetonitrile Solution

Review—Electrocatalytic Oxidation of Alcohols Using Chemically Modified Electrodes: A Review

Synthesis of p-cymene by the electrocatalytic oxidation of α-terpinene and γ-terpinene

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