Selective Monohydrocyanation of Diimine using Potassium Hexacyanoferrate(II)-Benzoyl Chloride Reagent System as a Cyanide Source

Li, Zheng; Wen, Fei; Yang, Jingya

doi:10.1007/s12039-016-1191-0

J Chem Sci

2016

DOI: 10.1007/s12039-016-1191-0

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Selective Monohydrocyanation of Diimine using Potassium Hexacyanoferrate(II)-Benzoyl Chloride Reagent System as a Cyanide Source

Zheng Li

Fei Wen

Jingya Yang

Abstract: The selective monohydrocyanation of diimines using potassium hexacyanoferrate(II)-benzoyl chloride reagent system as a cyanide source under catalyst-free condition is described. The advantages of this protocol are the non-toxic, non-volatile and inexpensive cyanide source, high yield, and simple work-up procedure.

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Cited by 3 publications

References 33 publications

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Palladium‐Catalyzed One‐Pot Four‐Component Synthesis of β‐Cyano‐α,β‐unsaturated Ketones Using Calcium Carbide as an Acetylene Source and Potassium Hexacyanoferrate(II) as an Eco‐Friendly Cyanide Source

Hao

2019

Adv Synth Catal

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Palladium-catalyzed one-pot four-component synthesis of β-cyano-α,β-unsaturated ketones by the reactions of aryl halides, calcium carbide, potassium hexacyanoferrate(II) and aroyl chlorides is described. The salient features of this protocol are the direct use of easy-to-handle acetylene source and eco-friendly cyanide source, wide scope of substrates with good functional group tolerance, and simple work-up procedure.

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Palladium‐Catalyzed One‐Pot Four‐Component Synthesis of β‐Cyano‐α,β‐unsaturated Ketones Using Calcium Carbide as an Acetylene Source and Potassium Hexacyanoferrate(II) as an Eco‐Friendly Cyanide Source

Hao

2019

Adv Synth Catal

Self Cite

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One‐Pot Multi‐Component Synthesis of Triarylacrylonitriles Directly by Using CaC₂ as a Concise Acetylene Source and K₄[Fe(CN)₆] as an Eco‐Friendly Cyanide Source

Song

2018

Eur J Org Chem

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An efficient method for the one‐pot multicomponent synthesis of triarylacrylonitriles from various aryl iodides directly by using calcium carbide as a concise acetylene source and potassium hexacyanoferrate(II) as an eco‐friendly cyanide source is described. This protocol benefits from safe, inexpensive and easy‐to‐handle starting materials, good substrate tolerance and simple work‐up procedure.

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Hydrocyanation of 2-arylmethyleneindan-1,3-diones using potassium hexacyanoferrate(II) as a nontoxic cyanating agent

Zheng

Hao

et al. 2019

Green Processing and Synthesis

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The hydrocyanation of 2-arylmethyleneindan-1,3-diones with potassium hexacyanoferrate(II) as a nontoxic cyanating agent to synthesize 2-(1,3-dioxoindan-2-yl)-2-arylacetonitriles in the presence of benzoyl chloride as a promoter and potassium carbonate as a base by a one-pot procedure is described. The use of nontoxic and inexpensive cyanide source, high yield and simple workup procedures are the advantages of this protocol.

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Selective Monohydrocyanation of Diimine using Potassium Hexacyanoferrate(II)-Benzoyl Chloride Reagent System as a Cyanide Source

Cited by 3 publications

References 33 publications

Palladium‐Catalyzed One‐Pot Four‐Component Synthesis of β‐Cyano‐α,β‐unsaturated Ketones Using Calcium Carbide as an Acetylene Source and Potassium Hexacyanoferrate(II) as an Eco‐Friendly Cyanide Source

Palladium‐Catalyzed One‐Pot Four‐Component Synthesis of β‐Cyano‐α,β‐unsaturated Ketones Using Calcium Carbide as an Acetylene Source and Potassium Hexacyanoferrate(II) as an Eco‐Friendly Cyanide Source

One‐Pot Multi‐Component Synthesis of Triarylacrylonitriles Directly by Using CaC₂ as a Concise Acetylene Source and K₄[Fe(CN)₆] as an Eco‐Friendly Cyanide Source

Hydrocyanation of 2-arylmethyleneindan-1,3-diones using potassium hexacyanoferrate(II) as a nontoxic cyanating agent

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Selective Monohydrocyanation of Diimine using Potassium Hexacyanoferrate(II)-Benzoyl Chloride Reagent System as a Cyanide Source

Cited by 3 publications

References 33 publications

Palladium‐Catalyzed One‐Pot Four‐Component Synthesis of β‐Cyano‐α,β‐unsaturated Ketones Using Calcium Carbide as an Acetylene Source and Potassium Hexacyanoferrate(II) as an Eco‐Friendly Cyanide Source

Palladium‐Catalyzed One‐Pot Four‐Component Synthesis of β‐Cyano‐α,β‐unsaturated Ketones Using Calcium Carbide as an Acetylene Source and Potassium Hexacyanoferrate(II) as an Eco‐Friendly Cyanide Source

One‐Pot Multi‐Component Synthesis of Triarylacrylonitriles Directly by Using CaC2 as a Concise Acetylene Source and K4[Fe(CN)6] as an Eco‐Friendly Cyanide Source

Hydrocyanation of 2-arylmethyleneindan-1,3-diones using potassium hexacyanoferrate(II) as a nontoxic cyanating agent

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Product

Resources

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One‐Pot Multi‐Component Synthesis of Triarylacrylonitriles Directly by Using CaC₂ as a Concise Acetylene Source and K₄[Fe(CN)₆] as an Eco‐Friendly Cyanide Source