Selective Inhibition Mechanisms of Fe(III) in the Flotation of Lepidolite

Abstract

Lepidolite, crucial for lithium extraction, is primarily processed through flotation. However, conventional flotation inhibitors pose environmental challenges. This study introduces Fe(III) as a selective and eco-friendly inhibitor in lepidolite flotation. We investigated its impact on flotation performance and interaction mechanisms with feldspar, quartz, and lepidolite. Adsorption studies revealed that dodecylamine (DDA) selectively adsorbs onto lepidolite when Fe(III) is present. Consistent contact angle and flotation results showed reduced hydrophobicity and recovery rates for feldspar and quartz, with minimal impact on lepidolite. Zeta potential measurements indicated lower potentials for feldspar and quartz compared to lepidolite. Notably, the addition of Fe(III) altered the isoelectric points of quartz and feldspar, suggesting stronger Fe(III) adsorption on these minerals. Infrared spectroscopy and X-ray photoelectron spectroscopy confirmed reduced DDA adsorption on feldspar and quartz surfaces due to Fe(III) adsorption, while DDA adsorption on lepidolite remained largely unaffected. The mechanism underlying Fe(III)’s selective inhibition on feldspar and quartz involves their more negative surfaces compared to lepidolite, which facilitates Fe(III) adsorption and inhibits DDA adsorption. This study offers insights into mechanisms relevant to systems using metal ions as depressants, providing valuable references for similar research.