Selective hydrogenation of citral over Au-based bimetallic catalysts in supercritical carbon dioxide

Abstract

Selective hydrogenation of citral was investigated over Au-based bimetallic catalysts in the environmentally benign supercritical carbon dioxide (scCO 2 ) medium. The catalytic performances were different in citral hydrogenation when Pd or Ru was mixed (physically and chemically) with Au. Compared with the corresponding monometallic catalyst, the total conversion and the selectivity to citronellal (CAL) were significantly enhanced over TiO 2 supported Pd and Au bimetallic catalysts (physically and chemically mixed); however, the conversion and selectivity did not change when Ru was physically mixed with Au catalyst compared to the monometallic Ru/TiO 2 , and the chemically mixed Ru-Au/TiO 2 catalyst did not show any activity. The effect of CO 2 pressure on the conversion of citral and product selectivity was significantly different over the Au/TiO 2 , Pd-Au/TiO 2 , and Pd/TiO 2 catalysts. It was assumed to be ascribed to the difference in the interactions between Au, Pd nanoparticles and CO 2 under different CO 2 pressures.

Hydrodeoxygenation of phenol as a bio-oil model compound over intimate contact noble metal–Ni2P/SiO2 catalysts

“…Thus, in comparison with the pure noble metal or Ni 2 P catalysts, the synergistic effect of the hydrodeoxygenation from Pd and the deoxygenation and carbonyl hydrogenation from Ni 2 P gives rise to the increment in the hydrodeoxygenation activity and the differences in the selectivity of the noble metal-Ni 2 P catalysts as well as higher reaction temperatures and longer times. In addition, the catalytic activities over the supported catalysts were compared with that of a mixture of 1% Pd/SiO 2 and 10% Ni 2 P/SiO 2 17 (Fig. 4 and Table S1 †).…”