Selective Fabrication of Robust and Multifunctional Super Nonwetting Surfaces by Diverse Modifications of Zirconia–Ceria Nanocomposites

Abstract

The creation of surfaces with various super nonwetting properties is an ongoing challenge. We report diverse modifications of novel synthesized zirconia–ceria nanocomposites by different low surface energy agents to fabricate nanofluids capable of regulating surface wettability of mineral substrates to achieve selective superhydrophobic, superoleophobic–superhydrophilic, and superamphiphobic conditions. Surfaces treated with these nanofluids offer self-cleaning properties and effortless rolling-off behavior with sliding angles ≤7° for several liquids with surface tensions between 26 and 72.1 mN/m. The superamphiphobic nanofluid coating imparts nonstick properties to a solid surface whereby liquid drops can be effortlessly displaced on the coating with a near-zero tilt and conveniently lifted off using a needle tip, leaving no trace. Further, the superamphiphobic surface demonstrates good oil repellency toward ultralow surface tension liquids such as n-hexane and n-heptane. The superoleophobic–superhydrophilic surface repels oil droplets well regardless of whether it is in the air or underwater conditions. In addition, reaping the benefits of the ZrO2–CeO2 nanocomposites’ photocatalysis feature, the superoleophobic–superhydrophilic coating exhibits self-cleaning ability by the degradation of color dyes. Modification of the wettability of substrates is carried out by a cost-effective and facile solution-immersion approach, which creates surfaces with hierarchical nano-submicron-scaled structures. The multipurpose coated surfaces have outstanding durability and mechanical stability. They also resist well high-temperature–high-pressure conditions, which will provide various practical applications in different fields, including the condensate banking removal in gas reservoirs or the separation of oil/water mixtures.

Multifunctional Amphiphobic Coating toward Ultralow Interfacial Adhesion of Hydrates

“…Other studies also reported that hydrophobic surfaces have lower nucleation and growth rates than hydrophilic surfaces. − Therefore, designing a multifunctional protective coating allowing simultaneous inhibition of hydrate nucleation and adhesion would be a simple but promising solution for anti-hydrate on a specific substrate surface. It is worth noting that most coatings suffer from low durability under harsh conditions, such as environments with oil pollution or salt corrosion, which results in a significant change in their surface chemistry and a great deterioration in their anti-hydrate performance . Considering the intense repellency to a variety of liquids into consideration, the amphiphobic coating, which is defined as superhydrophobicity and oleophobicity with super anti-wetting properties, would be a potential candidate for durable anti-hydrate in a variety of environments.…”

“…It is worth noting that most coatings suffer from low durability under harsh conditions, such as environments with oil pollution or salt corrosion, which results in a significant change in their surface chemistry and a great deterioration in their anti-hydrate performance. 17 Considering the intense repellency to a variety of liquids into consideration, the amphiphobic coating, which is defined as superhydrophobicity and oleophobicity with super anti-wetting properties, 18 would be a potential candidate for durable anti-hydrate in a variety of environments. However, to the best of our knowledge, relevant studies regarding anti-hydrates using an amphiphobic coating…”