2024
DOI: 10.1002/chem.202401339
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Selective Electrochemical Oxygen Reduction to Hydrogen Peroxide by Confinement of Cobalt Porphyrins in a Metal‐Organic Framework

Dana Rademaker,
Stefania Tanase,
Hongrui Kang
et al.

Abstract: Sustainable alternatives for the energy intensive synthesis of H2O2 are necessary. Molecular cobalt catalysts show potential but are typically restricted by undesired bimolecular pathways leading to the breakdown of both H2O2 and the catalyst. The confinement of cobalt porphyrins in the PCN‐224 metal‐organic framework leads to an enhanced selectivity towards H2O2 and stability of the catalyst. Consequently, oxygen can now be selectively reduced to hydrogen peroxide with a stable conversion for at least 5 h, il… Show more

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