Selective complexation between a novel bowl-shaped molecule and Fe3+ or ions

A first non‐ditopic system for selective recognition and binding of the higher alkali fluorides (KF, RbF, and CsF) is reported. Specific ion‐pair recognition was achieved by using vasarenes, a new class of self‐assembled bowl‐shaped compounds that show specific affinity toward the ion pairs and display no affinity for either the “free” cation or the anion. Vasarenes precipitate the higher alkali fluorides from solution, thus showing promising potential in separation processes.

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Selective Recognition of the Higher Alkali Fluoride Ion Pairs by a Class of Coordination‐Driven Non‐Ditopic Ligands

Almog

Gavish-Abramovich

Rozin

et al. 2012

Eur J Inorg Chem

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Selective complexation between a novel bowl-shaped molecule and Fe3+ or ions

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Selective Recognition of the Higher Alkali Fluoride Ion Pairs by a Class of Coordination‐Driven Non‐Ditopic Ligands

Selective Recognition of the Higher Alkali Fluoride Ion Pairs by a Class of Coordination‐Driven Non‐Ditopic Ligands

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