Selective catalytic synthesis of new terpenic chlorides using NaDCC as an eco-friendly and highly stable FAC agent

Labyad, Salim Adam; Mekkaoui, Ayoub Abdelkader; Laayati, Mouhsine; Orfi, Hamza; El Firdoussi, Larbi; El Houssame, Soufiane

doi:10.1039/d3ra05792e

RSC Adv.

2023

DOI: 10.1039/d3ra05792e

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Selective catalytic synthesis of new terpenic chlorides using NaDCC as an eco-friendly and highly stable FAC agent

Salim Adam Labyad,

Ayoub Abdelkader Mekkaoui,

Mouhsine Laayati

et al.

Abstract: A simple, mild and efficient scope pathway for selective catalytic chlorination of terpenic olefins is investigated using sodium dichloroisocyanurate (NaDCC) as highly efficient chlorination agent combined with readily available Lewis acid catalyst.

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2024

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Cited by 2 publications

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Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl₃ as the Dichlorination Reagent

Li,

Qiu,

Ren

et al. 2024

ChemistrySelect

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We report a ligand‐to‐metal charge‐transfer (LMCT) process that used ferric (III) chloride as efficient chlorination reagent to mediate the vicinal dichlorination of alkenes. Under 420 nm LED light, the easily available and safe ferric (III) chloride could facilitate various alkenes to transform as 1,2‐dichloride compounds with good to excellent yields (19 examples). The strategy showed a more economic protocol than CuCl2, and provided a significant reference for the light‐Induced dichlorination in industrial catalysis.

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Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl₃ as the Dichlorination Reagent

Li,

Qiu,

Ren

et al. 2024

ChemistrySelect

View full text Add to dashboard Cite

show abstract

FeCl3 induced sonochemical heteroarylation: Synthesis of meridianin alkaloid analogues for their in silico/in vitro evaluation against SIRT1

Adapa,

Mandava,

Kodali

et al. 2024

Journal of Molecular Structure

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Selective catalytic synthesis of new terpenic chlorides using NaDCC as an eco-friendly and highly stable FAC agent

Abstract: A simple, mild and efficient scope pathway for selective catalytic chlorination of terpenic olefins is investigated using sodium dichloroisocyanurate (NaDCC) as highly efficient chlorination agent combined with readily available Lewis acid catalyst.

Cited by 2 publications

References 71 publications

Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl₃ as the Dichlorination Reagent

Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl₃ as the Dichlorination Reagent

FeCl3 induced sonochemical heteroarylation: Synthesis of meridianin alkaloid analogues for their in silico/in vitro evaluation against SIRT1

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Selective catalytic synthesis of new terpenic chlorides using NaDCC as an eco-friendly and highly stable FAC agent

Abstract: A simple, mild and efficient scope pathway for selective catalytic chlorination of terpenic olefins is investigated using sodium dichloroisocyanurate (NaDCC) as highly efficient chlorination agent combined with readily available Lewis acid catalyst.

Cited by 2 publications

References 71 publications

Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl3 as the Dichlorination Reagent

Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl3 as the Dichlorination Reagent

FeCl3 induced sonochemical heteroarylation: Synthesis of meridianin alkaloid analogues for their in silico/in vitro evaluation against SIRT1

Contact Info

Product

Resources

About

Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl₃ as the Dichlorination Reagent

Light‐Induced Vicinal Dichlorination of Alkenes Using FeCl₃ as the Dichlorination Reagent