Selective C(sp3)–H bond aerobic oxidation enabled by a π-conjugated small molecule-oxygen charge transfer state
Panyi Huang,
Yan Xu,
Haijing Song
et al.
Abstract:Due to the high oxidation potential of arene and alkene, previous methods of benzylic and allylic C-H oxidation necessitated the use of strong oxidizing agents, metal catalysts, or free radical...
The EDA complex photochemistry is initiated on a ground-state associate bimolecule capable of intermolecular electron transfer, channelling chemical synthesis via a specific radical-based mechanistic pathway. Herein, we switch on the...
The EDA complex photochemistry is initiated on a ground-state associate bimolecule capable of intermolecular electron transfer, channelling chemical synthesis via a specific radical-based mechanistic pathway. Herein, we switch on the...
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