Sectoral and growth rate control on elemental uptake by individual calcite crystals

Mining Minerals and Critical Raw Materials from Bittern: Understanding Metal Ions Fate in Saltwork Ponds

“…calcite) is a phenomenon commonly observed in natural and laboratory systems. Recently, Gabitov et al (Gabitov et al, 2021) evaluated the elemental distribution by using partition coefficients of trace and minor elements (e.g. Li, B, Mg, and Sr) in calcite crystal faces along the mineral growth stages.…”

Effect of growth rate on nickel and cobalt incorporation in aragonite

“…The growth entrapment model (GEM) developed by Watson (Watson and Liang 1995;Watson, 1996;2004), can likely qualitatively explain the dependence of distribution coefficients on growth rate observed in this study. In fact, it has been previously used to describe the incorporation of both monoand divalent foreign elements (such as Mg 2+ , Ba 2+ , Li + , Na + ) in CaCO3 (e.g., Gabitov et al, 2008Gabitov et al, , 2011Gabitov et al, , 2021Mavromatis et al, 2013Mavromatis et al, , 2018Füger et al, 2019;Goetschl et al, 2019).…”

A high-pressure structural transition of norsethite-type BaFe(CO3)2: Comparison with BaMg(CO3)2 and BaMn(CO3)2

“…Partial cation substitution in carbonates is very common in natural samples, and the effects of substitution with various compositions and proportions on the physical and chemical properties of carbonates were extensively studied (e.g., Reeder and Dollase 1989;Lin et al 2012;Palaich et al 2015;Cerantola et al 2017;Zhao et al 2020;Gabitov et al 2021). Mn 2+ or Fe 2+ cations can often be incorporated into the crystal structures in double carbonates, such as kutnahorite, ankerite, and norsethitetype BaMn(CO 3 ) 2 (Rividi et al 2010;Efthimiopoulos et al 2017;Wang et al 2022).…”