2023
DOI: 10.1039/d3tc00652b
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Second-order nonlinear optical organic crystals based on a “click” compound

Abstract: Click chemistry has been employed for the fabrication of second-order nonlinear optical organic crystals BPTA with efficient second harmonic generation responses.

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“…SHG signals related to the polarization angle were collected at intervals of 10° in order to study the impact of polarization on the SHG response. The polarization diagram shows that the profile of the curve can be accurately fitted to the cos 4θ function (Figure b), which is consistent with the earlier results. The polarization dependence of R -2-mpip­[SnBr 3 ]Br exhibits a typical two-lobe shape and the greatest SHG signals at about 80 and 260°. For the p -analyzer, the computed polarization ratio, ρ = ( I max – I min )/( I max + I min ), was found to be 67.8%.…”
Section: Resultssupporting
confidence: 89%
“…SHG signals related to the polarization angle were collected at intervals of 10° in order to study the impact of polarization on the SHG response. The polarization diagram shows that the profile of the curve can be accurately fitted to the cos 4θ function (Figure b), which is consistent with the earlier results. The polarization dependence of R -2-mpip­[SnBr 3 ]Br exhibits a typical two-lobe shape and the greatest SHG signals at about 80 and 260°. For the p -analyzer, the computed polarization ratio, ρ = ( I max – I min )/( I max + I min ), was found to be 67.8%.…”
Section: Resultssupporting
confidence: 89%