Second-order nonlinear optical-active organic Zn(II)-hexaborate(2-) complex: Insights into structure, electrical and optical properties

Nabil, Jamai; Othmani, Abdelhak; Wang, Kai; Qian, Shuhang; Akriche, Samah

doi:10.1016/j.jssc.2022.123065

Cited by 3 publications

(1 citation statement)

References 52 publications

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“…It attracts the main focus of interest in academic and industrial studies because of their rich structures and specially their great aptitude to be coordinated with other species like d-elements (Cu 2+ , Co 2+ , Ni 2+ ….) and organic cations [7][8][9][10][11][12][13][14]. In fact, this great synergy arouses novel coordination metal complexes with signi cant optical and magnetic properties speci cally owing to the existence of electrons in the d orbital (paired or unpaired).For example, Mohammed A.…”

Section: Introductionmentioning

confidence: 99%

Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties

Karoui

Maalaoui

Duval

et al. 2023

Preprint

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Two new paramagnetic hybrid cobalt(II)-hexaborate(2-) based semiorganic complexes; (2A3MP)2[Co{κ3O-B6O7(OH)6}2].2H2O(1) and (2A4MP)2[Co{κ3O-B6O7(OH)6}2].2H2O (2)(2A3MP = 2-amino-3-methylpyridinium, 2A4MP = 2-amino-4-methylpyridinium)have been obtainedand characterized by X-ray diffraction, FT-IR, TG-DTA, optical and magnetic measurements. X-ray diffraction revealed two isostructural lattices with octahedral coordination of Co(II) complexes of bis(κ3O-donor hexaborate(2-)) ligands, [Co{κ3O-B6O7(OH)6}2]2-. The hydrated oxidopolyborate anions are extensively H-bounded to perform 3D-porous supramolecular anionic frameworks. In both 1 and 2 isostructures, 2A3MP and 2A4MP cations are pendant in the created voids of the inorganic frameworks through a set of H-bonds with 8.5 % and 60.5%H…O/O…H inter-contact contributions, respectively for 1 and 2 as confirmed by Hirshfield surfaces analysis. The optical band gap of Co(II) complexes range between 2.72 and 3.13 eV. Both compounds exhibited well-resolved paramagnetic properties with magnetic susceptibility values ranged between 0.9552 and 0.0088 cm3.mol-1, typical of octahedral Co(II) complexes.

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Section: Introductionmentioning

confidence: 99%

Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties

Karoui

Maalaoui

Duval

et al. 2023

Preprint

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Facile synthesis of paramagnetic Co(II)-hexaborate(2-)-based semi-organic complexes: a combined investigation on X-ray crystal structure, Hirshfeld surfaces analysis, optical and magnetic properties

Karoui,

Maalaoui,

Duval

et al. 2023

Transit Met Chem

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Crystal structure of MgK_0.5[B₆O₁₀](OH)_0.5·0.5H₂O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate]

Qiu

Song

2022

Acta Cryst E

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The solvothermal reaction of H3BO3, KCF3SO3, Mg(CF3SO3)2 and pyridine led to a new alkali- and alkaline-earth-metal borate, MgK0.5[B6O10](OH)0.5·0.5H2O. Its structure features an intricate three-dimensional framework built from [B6O13]8− clusters, thus resulting in a six-connected achiral net with high symmetry. Each [B6O13]8− building block is composed of three trigonal BO3 and three tetrahedral BO4 units, with these BO4 units being further connected to neighboring BO3 units, giving rise to an oxoboron cluster of the general formula [B6O10]2−.

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Second-order nonlinear optical-active organic Zn(II)-hexaborate(2-) complex: Insights into structure, electrical and optical properties

Cited by 3 publications

References 52 publications

Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties

Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties

Facile synthesis of paramagnetic Co(II)-hexaborate(2-)-based semi-organic complexes: a combined investigation on X-ray crystal structure, Hirshfeld surfaces analysis, optical and magnetic properties

Crystal structure of MgK_0.5[B₆O₁₀](OH)_0.5·0.5H₂O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate]

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Second-order nonlinear optical-active organic Zn(II)-hexaborate(2-) complex: Insights into structure, electrical and optical properties

Cited by 3 publications

References 52 publications

Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties

Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties

Facile synthesis of paramagnetic Co(II)-hexaborate(2-)-based semi-organic complexes: a combined investigation on X-ray crystal structure, Hirshfeld surfaces analysis, optical and magnetic properties

Crystal structure of MgK0.5[B6O10](OH)0.5·0.5H2O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate]

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Crystal structure of MgK_0.5[B₆O₁₀](OH)_0.5·0.5H₂O, poly[dimagnesium potassium bis(hexaborate) hydroxide monohydrate]