Let E be a vector bundle over a smooth curve C, and S = PE the associated projective bundle. We describe the inflectional loci of certain projective models ψ : S P n in terms of Quot schemes of E. This gives a geometric characterisation of the Segre invariant s1(E), which leads to new geometric criteria for semistability and cohomological stability of bundles over C. We also use these ideas to show that for general enough S and ψ, the inflectional loci are all of the expected dimension. An auxiliary result, valid for a general subvariety of P n , is that under mild hypotheses, the inflectional loci associated to a projection from a general centre are of the expected dimension.