Abstract:The textile industry is a sector completely dependent on water for its full functioning; on the other hand, water represents a very high cost in the production process. The textile chemical processing area is mainly responsible for the large consumption of water. On the opposite side of this high consumption there is an evident water crisis worldwide. That fact has led to many problems to textile companies, mainly for the preparation, dyeing and printing sectors. This present work focuses on an ecologically fr… Show more
“…Since 2000 several papers have demonstrated that organochlorinated compounds, pharmaceuticals, plasticizers, industrial additives, among others, are present in seawater causing its pollution [20] , [76] , [77] , [78] . Also, we can mention that seawater has great potential as a processing medium for dyeing steps in the textile industry, resulting in seawater waste loaded with dyes [79] , [80] . Therefore, many proofs of concept about the sonochemical treatment of seawater containing organic pollutants have been published, which are shown below.…”
Section: Elimination Of Organic Pollutants In Seawater By Ultrasoundmentioning
Highlights
Sonodegradation of organic pollutants in ions-rich matrices is critically reviewed.
Ultrasound is able to degrade pollutants of diverse nature in ions-rich matrices.
Low concentrations of contaminants favor degradation in mineral water and seawater.
Efficient pollutants sonodegradation in mineral water or seawater but action in urine is limited.
Ecotoxicity and transformations after ultrasound action on matrices must be tested.
“…Since 2000 several papers have demonstrated that organochlorinated compounds, pharmaceuticals, plasticizers, industrial additives, among others, are present in seawater causing its pollution [20] , [76] , [77] , [78] . Also, we can mention that seawater has great potential as a processing medium for dyeing steps in the textile industry, resulting in seawater waste loaded with dyes [79] , [80] . Therefore, many proofs of concept about the sonochemical treatment of seawater containing organic pollutants have been published, which are shown below.…”
Section: Elimination Of Organic Pollutants In Seawater By Ultrasoundmentioning
Highlights
Sonodegradation of organic pollutants in ions-rich matrices is critically reviewed.
Ultrasound is able to degrade pollutants of diverse nature in ions-rich matrices.
Low concentrations of contaminants favor degradation in mineral water and seawater.
Efficient pollutants sonodegradation in mineral water or seawater but action in urine is limited.
Ecotoxicity and transformations after ultrasound action on matrices must be tested.
“…They make up 70 % of all dyes and are used in industries like printing, food, pharmaceuticals, and cosmetics. [8][9][10] The conventional method for producing these compounds is through diazo-coupling, which involves combining a diazonium salt with the appropriate active methylene compound. [11] Azo-compounds have been shown to possess intriguing biological properties, including in vitro antimicrobial activity.…”
Section: Introductionmentioning
confidence: 99%
“…Azo‐compounds are brightly colored dyes, characterized by the presence of an ‐N=N‐ double bond between two aromatic or heterocyclic rings. They make up 70 % of all dyes and are used in industries like printing, food, pharmaceuticals, and cosmetics [8–10] . The conventional method for producing these compounds is through diazo‐coupling, which involves combining a diazonium salt with the appropriate active methylene compound [11] .…”
A three-component protocol was established to efficiently synthesize (chromene-thiazole) and related arylazo analogs in good to excellent yields. The desired products were prepared by reacting the appropriate salicylaldehydes, 2-cyanothioacetamide, and chloroacetone or hydrazonyl chlorides. Using piperidine as a mediator in ethanol at 80 °C for 4 -6 h, the three-component protocol produce the target hybrids in 87 -96 % yields. The newly synthesized products showed a broad range of antibacterial activity. The addition of an arylazo unit at the chromene-C6 position significantly improved the antibacterial activity, while the impact of adding an arylazo group at the thiazole-C5 position varied based on the electronic characteristics of the para-substituted arene unit. Generally, series that is linked to two arylazo units, one at chromene-C6 and the other at thiazole-C5, showed the best activity. Some new hybrids showed effective antibacterial activity than ciprofloxacin with MIC/ MBC values up to 1.9/3.9 μM against S. aureus and E. coli. Additionally, they demonstrated better effectiveness against MRSA ATCC:33591 and ATCC:43300 compared to linezolid, with MIC/MBC values up to 4.0/16.1 and 3.9/ 15.6 μM, respectively. The data predicted for the physicochemical properties, lipophilicity, pharmacokinetics, and drug-likeness of new arylazo-based chromene-thiazole hybrids evaluated by SwissADME. As a result of the above, products that are linked to two arylazo units can be considered drug-like scaffolds.
“…The most common one is dyeing. When diazonium salts undergo diazo-coupling reactions, diazo compounds are produced with great coloring features [2,3], and some of the important diazo dyes are shown in Figure 1a. Other than dyeing, some of the diazo compounds have antimicrobial, anticancer, antibacterial, antioxidant, antibiotic, antifungal and anti-HIV activity (Figure 1b) [4][5][6][7].…”
Diazonium salts were found to be useful intermediates for many applications. Although few salts were isolated, they were found to be short lived. Charged boron cages have been known to be weakly coordinating anions. The cages were used to isolate short lived cations for characterizations and further reactions. In this study , we have facilitated dodecaborate dianion and carborate anion to isolate and characterize diazonium cations. With these cages, it was found that diazonium cation to be stable more than a month at ambient conditions.
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