Photochemical
weathering leads to degradation of microplastics
and releases chemical additives, polymeric fragments, and/or byproducts.
This study evaluated the release kinetics of organotin compounds (OTCs)
from three different sized (10–300 μm) polyvinyl chloride
(PVC) microplastics under UV- and visible light irradiation. Four
OTCs, dimethyltin (DMT), monomethyltin (MMT), dibutyltin (DBT), and
monobutyltin (MBT), were found to release from PVC particles after
24 h leaching in darkness ranging from 2 to 20 μg·g-PVC–1. Under UV/visible light irradiation, only DMT and
DBT were detectable, whereas MMT and MBT were not detected due to
rapid photodegradation. The total tin concentrations (including organic
and inorganic tins) in the aqueous phase monotonically increased under
light exposure. By contrast, they reached plateaus after 24 h in darkness,
confirming the photodegradation of OTCs. A release kinetics model
was established and correctly interpreted the microplastics size effect
on the OTC release process. Finally, the impacts of salinity and dissolved
organic matter (DOM) were investigated. The release and photodegradation
of OTCs were both inhibited at high salinity conditions, probably
due to the enhanced readsorption of OTCs on PVC microplastics and
the formation of halogen radicals that were less reactive toward neutral
OTCs. The presence of DOM, however, increased OTCs release probably
because the excited state triplet DOM (3DOM*) formed and
reacted with OTCs from PVC microplastics.