Seasonal assessment of the physico-chemical properties of surface water and sediments in the vicinity of a scrap metal recycling industry in Southwestern Nigeria
Abstract:The study assessed the seasonal variations in the physico-chemical properties of surface water and sediments in some villages located around a scrap metal recycling industry in Ile-Ife. This is with a view to monitor the impact of the industry on the quality of surrounding water. The three water bodies (one river, one stream and one pond) identified in the area were sampled every other month for ten months. Water and sediment were sampled from the water bodies and their physico-chemical properties were determi… Show more
“…The mean concentration of Ca 2+ is highest in pond 1 (0.112±0.032) mgkg -1 and lowest in pond 3 (0.065±0.018) mgkg -1 while the mean concentration of K + is highest in pond 3 (0.781±0.296) mgkg -1 and lowest in pond 2 (0.411±0.142) mgkg -1 within the sampling locations. The values of the ions obtained in the study are generally high in the pond which is in accordance with the report of Okoya et al (2020b) in a similar study but different locations.…”
Natural radionuclides pose a threat to the environment, because of the radioactivity they undergo. Water is said to be the sink of all pollutants including radionuclides and water pollution is a serious challenge due to the direct link between the adequacy of good quality water and the state of public health. The concentrations of uranium-238, thorium-232 and potassium-40 and ions in the selected water bodies around Ikirun Iron-smelting Industry were determined in wet and dry seasons to highlight possible radioactive pollution from the iron-smelting emissions. The radionuclides were analyzed using gamma spectroscopy. It was observed that 238U, 232Th, and 40K had their calculated annual effective dose (0.00004, 0.00003, and 0.010 mSvyr-1) to be below the WHO individual dose criterion of 0.1 mSvyr-1 and reference level of 1 mSvyr-1 in drinking water. The mean activity concentrations (AC) of U-238, Th-232 and K-40 in water were observed to be higher in the wet season (3.84±0.6, 2.37±0.5 and 15.83±1.3 Bqkg-1 respectively) than in the dry season (2.81±0.00, 0.92±0.00, and 10.2±0.00 Bqkg-1 respectively). The radionuclides, 238U, 232Th, and 40K also had their AC higher in sediment (40.50 ± 10.50, 66.24 ± 13.50 and 340.22 ± 9.00 BqL-1; Bqkg-1) than in water (1.28 ± 0.30, 0.26 ± 0.10 and 5.75 ± 0.70 Bqkg-1). The range of AC for 232Th, 238U, and 40K in water are 0.17 - 2.49 Bqkg-1, 1.01 - 4.04 Bqkg-1, and 3.98 - 17.48 Bqkg-1 respectively with 40K having the highest AC throughout the sampling locations. The result of anions in water samples for the sampling period are in the decreasing order of Cl- (3.55 - 106.95 mgL-1) < SO42- (0.25 - 15.82 mgL-1) < NO3- (0.01 - 0.49 mgL-1) while cations in water samples for the sampling period are in increasing order of Na+ (0.054 - 0.212 mgL-1) < Mg2+ (0.066 - 0.282mgL-1) < Ca2+ (0.077 -0.261mgL-1) < K+ (0.40-3.1 mgL-1), with potassium having the highest concentration range. The study observed no significant radionuclides pollution of water and sediment in the study area.
“…The mean concentration of Ca 2+ is highest in pond 1 (0.112±0.032) mgkg -1 and lowest in pond 3 (0.065±0.018) mgkg -1 while the mean concentration of K + is highest in pond 3 (0.781±0.296) mgkg -1 and lowest in pond 2 (0.411±0.142) mgkg -1 within the sampling locations. The values of the ions obtained in the study are generally high in the pond which is in accordance with the report of Okoya et al (2020b) in a similar study but different locations.…”
Natural radionuclides pose a threat to the environment, because of the radioactivity they undergo. Water is said to be the sink of all pollutants including radionuclides and water pollution is a serious challenge due to the direct link between the adequacy of good quality water and the state of public health. The concentrations of uranium-238, thorium-232 and potassium-40 and ions in the selected water bodies around Ikirun Iron-smelting Industry were determined in wet and dry seasons to highlight possible radioactive pollution from the iron-smelting emissions. The radionuclides were analyzed using gamma spectroscopy. It was observed that 238U, 232Th, and 40K had their calculated annual effective dose (0.00004, 0.00003, and 0.010 mSvyr-1) to be below the WHO individual dose criterion of 0.1 mSvyr-1 and reference level of 1 mSvyr-1 in drinking water. The mean activity concentrations (AC) of U-238, Th-232 and K-40 in water were observed to be higher in the wet season (3.84±0.6, 2.37±0.5 and 15.83±1.3 Bqkg-1 respectively) than in the dry season (2.81±0.00, 0.92±0.00, and 10.2±0.00 Bqkg-1 respectively). The radionuclides, 238U, 232Th, and 40K also had their AC higher in sediment (40.50 ± 10.50, 66.24 ± 13.50 and 340.22 ± 9.00 BqL-1; Bqkg-1) than in water (1.28 ± 0.30, 0.26 ± 0.10 and 5.75 ± 0.70 Bqkg-1). The range of AC for 232Th, 238U, and 40K in water are 0.17 - 2.49 Bqkg-1, 1.01 - 4.04 Bqkg-1, and 3.98 - 17.48 Bqkg-1 respectively with 40K having the highest AC throughout the sampling locations. The result of anions in water samples for the sampling period are in the decreasing order of Cl- (3.55 - 106.95 mgL-1) < SO42- (0.25 - 15.82 mgL-1) < NO3- (0.01 - 0.49 mgL-1) while cations in water samples for the sampling period are in increasing order of Na+ (0.054 - 0.212 mgL-1) < Mg2+ (0.066 - 0.282mgL-1) < Ca2+ (0.077 -0.261mgL-1) < K+ (0.40-3.1 mgL-1), with potassium having the highest concentration range. The study observed no significant radionuclides pollution of water and sediment in the study area.
“…It is fascinating to observe that these values align with the recommended limit of 200 mg/L and 600 mg/L as CaCO3 set by regulatory bodies[50,51,53]. These results are consistent with other studies conducted in the south-western region of Nigeria, which reported acidity values ranging from 5.0 mg/L to 12.0 mg/L as CaCO3 and alkalinity values ranging from 33.3 mg/L to 78.60 mg/L as CaCO3[60]. Further emphasizing the reliability of these findings, the control point exhibited an acidity value of 47.63 mg/L as CaCO3 and an alkalinity value of 44.69 mg/L as CaCO3, both falling well below the limits recommended by the regulatory bodies (see Table2).…”
Physicochemical, heavy metals and hydrocarbon parameters of fifteen surface water samples and fourteen sediment samples from the Alape River and its watershed in Igbokoda, South-Western Nigeria have been analysed. APHA and ASTM standard methods were employed in the analysis of the samples while obtained results were compared to DPR, NESREA, NSDWQ and WHO set standards. The mean pH values of the River and its watershed were found to be 6.78 and 7.25 respectively, falling within the recommended limit. In terms of DO, the mean values of 5.25 mg/L and 5.42 mg/L obtained were equally within the acceptable range for supporting aquatic organisms. Mean values of TS and salinity were relatively low, indicating favourable conditions. However, the mean total hardness value was considerably high. The River and its watershed exhibited low levels of O&G, TPH, and Cl-. The presence of organic matter was also observed, as demonstrated from the mean values of BOD and COD, suggesting some level of pollution. Furthermore, the sediments from the River contained detectable concentrations of some heavy metals; Fe, Pb, Cu, Mn, and Zn. The concentration of Fe exceeded the recommended limit set by NESREA. Overall, the research outcomes serve as valuable baseline data for future studies and offer insights to establish effective measures to prevent pollution in the event of industrialization in the area.
“…Preparation and sampling of wastewater: The water sampling bottles (2.5 L) were pre-cleaned according to standard methods for organic contamination sampling 13,14 . To prevent further contamination, the bottles were allowed to air dry for 24 hrs and the mouthparts were wrapped in aluminium foil until sampling.…”
Section: Characterization Of Sawdust Activated Carbon (Sac)mentioning
Background and Objective: In the aquatic environment, pesticides are the most studied class of organic toxins but their management has received little attention. The efficacy of activated carbon formed from sawdust as an adsorbent for pesticide removal from industrial wastewater was investigated as well as the effectiveness of conventional wastewater treatment processes for pesticide removal. It also compared the adsorbentʼs efficiency to activated carbon that is commercially available. Materials and Methods: The SEM-EDX, FTIR and the brunauer-emmett-teller (BET) analyzer were used to analyze sawdust-activated carbon (SAC) made from locally available sawdust. Batch adsorption experiment on simulated solutions of 2,2-Dichlorovinyl-dimethyl-phoshate (DDVP) at varied concentrations (0.001, 0.005, 0.01, 0.1 and 0.5 mg LG 1 ) using SAC. Other variables including pH, adsorbent dose and contact time were optimized. Results: The pH was 7.2±0.14, ash content was 3.1±0.00, moisture content was 2.0±0.32%, Brunner Emmett Teller surface area was 736±0.00 m 2 gG 1 , micropore volume was 0.3131±0.00 m 3 gG 1 and bulk density was 0.55±0.00, according to the SAC. In the untreated and company-treated wastewater samples, the percentage recoveries for DDVP were 86±0.71 and 88±1.41, respectively. In the adsorption of DDVP from industrial wastewater, the optimum parameters obtained during the simulation experiment were used. Sawdust activated carbon has higher adsorption efficiencies (89.06±0.014 and 88.62±0.962) than commercial activated carbon (80.94±2.744 and 77.50±0.410) for both untreated and company-treated wastewater, according to the findings. Conclusion: The sawdust-activated carbon can be used as a low-cost, high-performance and environment-friendly adsorbent when compared to commercial activated carbon for the removal of DDVP from wastewater.
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