Solar antineutrinos are absent in the standard solar model prediction. Consequently, solar
antineutrino searches emerge as a powerful tool to probe new physics capable of converting
neutrinos into antineutrinos. In this study, we highlight that neutrino self-interactions,
recently gaining considerable attention due to their cosmological and astrophysical implications,
can lead to significant solar antineutrino production. We systematically explore various types of
four-fermion effective operators and light scalar mediators for neutrino self-interactions. By
estimating the energy spectra and event rates of solar antineutrinos at prospective neutrino
detectors such as JUNO, Hyper-Kamiokande, and THEIA, we reveal that solar antineutrino searches
can impose stringent constraints on neutrino self-interactions and probe the parameter space
favored by the Hubble tension.