Sealing Treatment of Plasma-Sprayed Cr3C2-NiCr/Al2O3-TiO2 Coating by Aluminum Phosphate Sealant Containing Al2O3 Nanoparticles

Abstract

A typical structure of thermal spray coatings consisted of molten particles, semi-molten particles, oxides, pores, and cracks. These factors caused the porosity of sprayed coatings, leading to a significant influence on the coating properties, especially their wear-corrosion resistance. In this study, a post-spray sealing treatment of Cr 3 C 2 -NiCr/Al 2 O 3 -TiO 2 plasma-sprayed coatings was carried out, and then, their corrosion properties were evaluated, before and after the treatment. For the sealing process, aluminum phosphate (APP) containing Al 2 O 3 nanoparticles (~10 nm) was used. The permeability of APP into the sprayed coating was analyzed by SEM-EDS. The treatment efficiency for porosity and corrosion resistance of sprayed coatings was evaluated by electrochemical measurements, such as the potentiodynamic polarization and electrochemical impedance spectroscopy. The wear-corrosion resistance of the coating was examined in 3.5 wt.% NaCl circulation solution containing 0.25% SiO 2 particles. The sealing efficiency was evaluated by the percentage of the treated open pores in the coating. The obtained results showed that APP penetrated deeply through the coating and the incorporation of Al 2 O 3 nanoparticles into APP sealant improved the sealing efficiency by 20% of open pores in comparison with the sealant without nano-Al 2 O 3 . The effect of the post-treatment on corrosion protection of the sprayed coating has been discussed.

Effect of heat treatment on corrosion resistance of Al2O3-TiO2 ceramic coating impregnated with aluminum phosphate

“…The Biologic VSP-300 electrochemical measuring instrument coupled with EClab software was used to study the anti-corrosion/corrosion properties of the coating. The phase composition of the residual aluminum phosphate on the coating surface was investigated by X-ray diffraction (XRD D5005/ SIEMENS) at 25 o C with Cu-Kα radiation, 2θ angle scanning from 10 o to 70 o , a step width of 0.03 o [16,19]. The erosion-corrosion resistance of the sample was tested by centrifugal spinning method, rotation speed 1000 rpm, corrosion test time 168 hours, in 3.5 % NaCl solution containing 0.25 % SiO 2 particles causing erosion.…”