Sea Urchin‐Like MOF‐Derived Formation of Porous Cu₃P@C as an Efficient and Stable Electrocatalyst for Oxygen Evolution and Hydrogen Evolution Reactions

Abstract

Owning to the energy crisis and environmental pollution, it is urgent to develop an efficient and earth‐abundant electrocatalyst for water splitting. In this work, the Cu2O cubes are first synthesized through a modified precipitation method, and it is subsequently selected as the Cu2+ source to synthesize 3D MOF (metal‐organic framework, Cu‐BDC) nanoarray by a facile and efficient bottom‐up method. Next, porous Cu3P@C is prepared via the low‐temperature phosphorization of 3D Cu‐BDC nanoarray as a high‐performance electrocatalyst for oxygen and hydrogen evolution reactions (OER and HER). In particular, the effect of reaction temperature on the morphology of 3D Cu‐BDC precursor is studied in detail. Experimental results reveal that Cu3P@C‐120 derived from sea urchin‐like Cu‐BDC exhibits excellent electrocatalytic performance owning to the high special surface area, developed porous structure, and the uniform dispersion of Cu3P nanoparticles, which affords the current density of 10 mA cm−2 at low overpotentials of 300 and 124 mV for OER (alkaline medium) and HER (acidic medium) with Tafel slopes of 24 and 29 mV dec−1, respectively. Remarkably, Cu3P@C‐120 also exhibits an excellent durability for OER and HER, making it an efficient bifunctional electrocatalyst for application in the production of clean hydrogen fuel.

“Nano-garden cultivation” for electrocatalysis: controlled synthesis of Nature-inspired hierarchical nanostructures

“…17,18 Interesting nanostructures resembling natural shapes can be obtained. For instance, using solvothermal or hydrothermal strategies, ower-, [19][20][21][22][23] leaf-, 24,25 coral- [26][27][28][29][30] and seaurchin-like nanostructures have been reported recently, 31,32 demonstrating much enhanced performances in different applications. However, the biomimetic appearance of these patterns during the synthesis, in many cases, is not based on predictive mechanisms.…”

Fe3O4@chitosan‐bound boric acid composite as pH‐responsive reusable adsorbent for selective recognition and capture of cis‐diol‐containing shikimic acid

“…Figure C displays the narrow scans of C 1 s for Fe 3 O 4 @CT‐COOH‐BA in detail. The C 1 s signal can be divided into four binding energies located at 284.6, 286, 287.1 and 288.2 eV, which could be ascribed to C‐C, C‐O, C=O and C‐N bonding . respectively.…”

Metal‐organic frameworks‐derived novel nanostructured electrocatalysts for oxygen evolution reaction

“…To develop a Cu‐based OER catalyst using CuO 2 cubes, Rong et al 80 reported porous Cu 3 P@C (Cu 3 P@C‐120) directly synthesized from Cu‐based MOF (Cu‐BDC). The catalyst exhibited remarkable electrocatalytic ability due to the large surface area, porous structure, and the uniformly dispersed Cu 3 P nanoparticles, which exhibited a current density of 10 mA/cm 2 at a low overpotential of 300 mV (Figure 6C,D).…”