Screening of Ni based catalysts supported on metal oxides for liquid-phase hydrogenation of furfural to furfuryl alcohol

Qi, Jingbo; Ren, Yanbiao; Zhang, Lincai; Hu, Xun

doi:10.1039/d3nj02140h

Cited by 3 publications

(2 citation statements)

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“…However, its selective hydrogenation to generate FA was not effective. [67] Firstly, the strong interaction between the activated H* and Ni hindered the desorption of H* from the Ni surface, consequently impeding the subsequent hydrogenation process. [68] Secondly, due to the tendency of FF to adsorb on the Ni surface in a "lie-flat" configuration, the robust interaction between the C=C bond of the furan ring and the Ni site resulted in the excessive hydrogenation of FF.…”

Section: Ni-based Catalystsmentioning

confidence: 99%

“…As a non‐noble metal, nickel exhibits a remarkable combination of affordability, high hydrogen adsorption, and activation activity. However, its selective hydrogenation to generate FA was not effective [67] . Firstly, the strong interaction between the activated H* and Ni hindered the desorption of H* from the Ni surface, consequently impeding the subsequent hydrogenation process [68] .…”

Section: Conversion Of Ff To Renewable Value‐added Chemicalsmentioning

confidence: 99%

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Advancements in the Heterogeneous Catalytic Hydrogenation of Furfural to Downstream Products

Zhang,

Ma,

Yang

2024

ChemistrySelect

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Furfural is a 5‐membered heterocyclic compound derived from biomass and can be converted into various chemicals and biofuels through hydrogenation. Furfural conversion invariably requires the involvement of catalysts. The performance of these catalysts predominantly hinges on the characteristics of the metal active sites, the properties of the support, and the regulation of reaction conditions. Therefore, the selection of metals and supports, the preparation methods of catalysts, as well as the determination of reaction solvents, temperature, pressure, and catalyst dosage are the factors that researchers need to consider. Based on this, this present review focuses on the production process and heterogeneous catalytic system selection of furfural hydrogenation to prepare downstream products since 2018. It provides a brief introduction to the corresponding catalytic reaction mechanisms, focuses on the effects of different metals and supports on catalytic performance, and provides an outlook on this research direction.

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Section: Ni-based Catalystsmentioning

confidence: 99%

Section: Conversion Of Ff To Renewable Value‐added Chemicalsmentioning

confidence: 99%

Advancements in the Heterogeneous Catalytic Hydrogenation of Furfural to Downstream Products

Zhang,

Ma,

Yang

2024

ChemistrySelect

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Supporting Nano Catalysts for the Selective Hydrogenation of Biomass‐derived Compounds

Su,

Zou,

et al. 2024

ChemSusChem

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The selective hydrogenation of biomass derivatives presents a promising pathway for the production of high‐value chemicals and fuels, thereby reducing reliance on traditional petrochemical industries. Recent strides in catalyst nanostructure engineering, achieved through tailored support properties, have significantly enhanced the hydrogenation performance in biomass upgrading. A comprehensive understanding of biomass selective upgrading reactions and the current advancement in supported catalysts is crucial for guiding future processes in renewable biomass. This review aims to summarize the development of supported nanocatalysts for the selective hydrogenation of the US DOE's biomass platform compounds derivatives into valuable upgraded molecules. The discussion includes an exploration of the reaction mechanisms and conditions in catalytic transfer hydrogenation (CTH) and high‐pressure hydrogenation. By thoroughly examining the tailoring of supports, such as metal oxide catalysts and porous materials, in nano‐supported catalysts, we elucidate the promoting role of nanostructure engineering in biomass hydrogenation. This endeavor seeks to establish a robust theoretical foundation for the fabrication of highly efficient catalysts. Furthermore, the review proposes prospects in the field of biomass utilization and address application bottlenecks and industrial challenges associated with the large‐scale utilization of biomass.

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Selective conversion of furfural to cyclopentanone over the N-doped CuNi alloy carbon materials derived from porphyrin-based bimetallic metal-organic frameworks

Cai,

Zhang,

et al. 2024

Fuel

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Screening of Ni based catalysts supported on metal oxides for liquid-phase hydrogenation of furfural to furfuryl alcohol

Abstract: Furfural, as a significant platform chemical, has established a unique connection between lignocellulosic biomass and the industry. Five types of nano metal oxides (MgO, TiO2, SiO2, ZrO2 and Al2O3) supported...

Cited by 3 publications

References 47 publications

Advancements in the Heterogeneous Catalytic Hydrogenation of Furfural to Downstream Products

Advancements in the Heterogeneous Catalytic Hydrogenation of Furfural to Downstream Products

Supporting Nano Catalysts for the Selective Hydrogenation of Biomass‐derived Compounds

Selective conversion of furfural to cyclopentanone over the N-doped CuNi alloy carbon materials derived from porphyrin-based bimetallic metal-organic frameworks

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