Scratch Resistance of High Velocity Oxy-Fuel Sprayed WC-20% Co Coatings Reinforced with Carbon Nanotubes

Abstract

Tungsten Carbide-20 weight % Cobalt (WC-20 wt% Co) coatings were extensively used material to achieve a combination of extreme hardness and excellent strength. Hence, an effort has been made to improve the toughening properties of WC-Co coatings through reinforcement of Carbon Nano-Tubes (CNTs) using High-Velocity Oxy-Fuel (HVOF) spraying process. In this work, 2 wt%, 4 wt%, and 6 wt% of CNTs were blended by the ball milling process with WC-Co powders. These composed powders were deposited by HVOF process on to the plain mild steel substrates. The scratch test analysis on as-sprayed coatings showed that due to the addition of CNTs on WC-Co coatings, the resistance to penetrate the coating surface increased. Also, by varying the percentage of CNTs in the coating system, the pores were reduced. This phenomenon is attributed to the toughening mechanism by forming a CNT bridge which avoids the formation of internal cracks.

Characteristics of reduced graphene oxide (rGO) mixed HVOF-sprayed nanostructured coatings

“…The Co 3 W 3 C phase is a binder matrix, and it is formed during the solidification of the coating. This phase can be seen only in the nanostructured coatings due to variations in cooling rates of different phases [51]. Additionally, this Co 3 W 3 C brittle phase formation reduces the compressive residual stresses in the coatings and enhances their fracture toughness to a great extent [52].…”