Abstract:The development of artificial organs and implants demands new materials with both processability and functionality. A series of star like poly(CL-co-TOSUO) copolymers with different molecular weights are synthesized via ring-opening polymerization. The polymers are modified with norbornene end groups for rapid photo-crosslinking. Due to the random insertion of 1,4,8-trioxaspiro-[4,6]-9-undecanone and well-constructed permanent chemical network, the photocrosslinked elastomers are more flexible and resilient th… Show more
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