<scp>D</scp>esigning scintillating coordination polymers using a dual-ligand synthetic approach

Arteaga, Ana; Lulich, Alice; Nyman, May; Surbella, Robert G.

doi:10.1039/d3ce00358b

CrystEngComm

2023

DOI: 10.1039/d3ce00358b

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Designing scintillating coordination polymers using a dual-ligand synthetic approach

Ana Arteaga

Alice Lulich

May Nyman

et al.

Abstract: Herein we report the synthesis and structural characterization of three new europium containing coordination polymers: [Eu(terpy)(2,6-ndc)1.5]·H2O (Linus Pauling (LP) 1), [Eu(terpy)(1,4-ndc)(1,4-Hndc)] (LP-2), and [Eu(phen)(2,6-ndc)1.5]·DMF (LP-3).

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2024

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Synthesis and Characterization of Highly Fluorinated Hydrophobic Rare–Earth Metal–Organic Frameworks (MOFs)

Abbas,

Murari,

Sheybani

et al. 2024

Materials

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Tuning a material’s hydrophobicity is desirable in several industrial applications, such as hydrocarbon storage, separation, selective CO2 capture, oil spill cleanup, and water purification. The introduction of fluorine into rare-earth (RE) metal–organic frameworks (MOFs) can make them hydrophobic. In this work, the linker bis(trifluoromethyl)terephthalic acid (TTA) was used to make highly fluorinated MOFs. The reaction of the TTA and RE3+ (RE: Y, Gd, or Eu) ions resulted in the primitive cubic structure (pcu) exhibiting RE dimer nodes (RE-TTA-pcu). The crystal structure of the RE-TTA-pcu was obtained. The use of the 2-fluorobenzoic acid in the synthesis resulted in fluorinated hexaclusters in the face-centered cubic (fcu) framework (RE-TTA-fcu), analogous to the UiO-66 MOF. The RE-TTA-fcu has fluorine on the linker as well as in the cluster. The MOFs were characterized by powder X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetric analysis, and contact angle measurements.

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Synthesis and Characterization of Highly Fluorinated Hydrophobic Rare–Earth Metal–Organic Frameworks (MOFs)

Abbas,

Murari,

Sheybani

et al. 2024

Materials

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show abstract

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Designing scintillating coordination polymers using a dual-ligand synthetic approach

Abstract: Herein we report the synthesis and structural characterization of three new europium containing coordination polymers: [Eu(terpy)(2,6-ndc)1.5]·H2O (Linus Pauling (LP) 1), [Eu(terpy)(1,4-ndc)(1,4-Hndc)] (LP-2), and [Eu(phen)(2,6-ndc)1.5]·DMF (LP-3).

Cited by 1 publication

References 66 publications

Synthesis and Characterization of Highly Fluorinated Hydrophobic Rare–Earth Metal–Organic Frameworks (MOFs)

Synthesis and Characterization of Highly Fluorinated Hydrophobic Rare–Earth Metal–Organic Frameworks (MOFs)

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