( Bi ₁₉ S ₂₇ I ₃ ) _0.6667 nanorods with more negative potentials of conduction band as highly active photocatalysts under visible light

Abstract

Summary The rational design of photocatalysts with more negative potentials of the conduction band is of vital importance in improving the performance of photocatalysts for reduction reactions. In this work, highly crystalline and uniform (Bi19S27I3)0.6667 nanorods were firstly synthesized by a one‐step hydrothermal process. The formation of the (Bi19S27I3)0.6667 nanorods consists of nucleation and crystal growth in agglomerates of spherical particles. The obtained (Bi19S27I3)0.6667 nanorods with a narrow band gap of about 1.80 eV, a wide visible light absorption spectrum, and a more negative conduction band potential are capable of producing high‐reducibility electrons, and an efficiently photogenerated carriers separation capability. The results demonstrate that the (Bi19S27I3)0.6667 nanorods can be as efficient and stable photocatalysts for Cr(VI) photoreduction and RhB degradation reactions. The photocatalytic reduction efficiency of Cr(VI) over the (Bi19S27I3)0.6667 nanorods was determined to be more than 3 times those of the corresponding BiOI and Bi2S3 photocatalysts under visible light. The detailed formation mechanism of (Bi19S27I3)0.6667 nanorods and the reaction mechanism of Cr(VI) photoreduction were proposed based on various characterizations.

Nanostructured Metal Chalcohalide Photocatalysts: Crystal Structures, Synthesis, and Applications

“…Highly crystalline (Bi 19 S 27 I 3 ) 0.6667 nanorods were also synthesized for photocatalytic degradation of Cr(VI). 198 These iodide-based chalcohalide nanorods possess several advantages, like a narrow bandgap energy (1.8 eV), a high separation of charge carriers, and a more negative CB position. Taking advantage of these unique features, (Bi 19 S 27 I 3 ) 0.6667 nanorods were proved to be highly active and stable photocatalysts for Cr(VI) photoreduction.…”

“…This work provided a new strategy for the design of advanced chalco­halide-based photocatalysts for diverse applications. Highly crystalline (Bi 19 S 27 I 3 ) 0.6667 nanorods were also synthesized for photocatalytic degradation of Cr­(VI) . These iodide-based chalco­halide nanorods possess several advantages, like a narrow bandgap energy (1.8 eV), a high separation of charge carriers, and a more negative CB position.…”

BiOCl Nanosheets with Vacancy Containing (001) and (110) Facets for the Photocatalytic Degradation of Organic Contaminants

“…At present, photocatalysis is regarded as one of the most promising technologies for solving current environmental and energy problems. − However, the fast recombination of photogenerated charge carriers remains a major challenge for photocatalysts, which significantly retards the rapid development of photocatalytic technologies . Furthermore, photocatalysts with conventional bulk architectures still suffer from insufficient active sites, thus constraining the quantum efficiencies and slowing charge transfer kinetics .…”