Schrittweiser Abbau von weißem Phosphor: Experimentelle und computergestützte Studien zum Mechanismus der P4‐Hydrostannylierung
Jose Cammarata,
Franz F. Westermair,
Peter Coburger
et al.
Abstract:The hydrostannylation of white phosphorus (P4) allows this crucial industrial precursor to be easily transformed into useful P1 products via direct, ‘one pot’ (or even catalytic) procedures. However, a thorough mechanistic understanding of this transformation has remained elusive, hindering attempts to use this rare example of successful, direct P4 functionalization as a model for further reaction development. Here, we provide a deep and generalizable mechanistic picture for P4 hydrostannylation by combining D… Show more
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