Ultra-cold collisions of spin-polarized 24 Mg, 40 Ca, and 88 Sr in the metastable 3 P2 excited state are investigated. We calculate the long-range interaction potentials and estimate the scattering length and the collisional loss rate as a function of magnetic field. The estimates are based on molecular potentials between 3 P2 alkaline-earth atoms obtained from ab initio atomic and molecular structure calculations. The scattering lengths show resonance behavior due to the appearance of a molecular bound state in a purely long-range interaction potential and are positive for magnetic fields below 50 mT. A loss-rate model shows that losses should be smallest near zero magnetic field and for fields slightly larger than the resonance field, where the scattering length is also positive.PACS numbers: 32.10. Dk, 33.55.Be, 34.10.+x, 39.25.+k Exploring ultracold collision physics with metastable (nsnp) 3 P 2 alkaline-earth atoms [1,2,3,4,5] promises insights that complement those obtained from the more conventional atomic species used in laser cooling. Unlike alkali-metal atoms [6,7] the most-common alkaline-earth atoms have no nuclear spin, which greatly simplifies a theoretical description [8]. Furthermore, in contrast to metastable noble-gas collisions[9] the low electronic energy of the alkaline-earth metastable states ensures the absence of collisionally induced Penning or associative ionization.Atomic collisions in the ultracold regime play a crucial role on the road toward quantum degenerate gases. We show here that polarized metastable (nsnp) 3 P 2 alkaline earth systems with projection m = 2 along the magnetic field might satisfy the key requirements for this quest: a positive scattering length and a favorable ratio of elastic to inelastic collision rates for certain magnetic field strengths. In addition, we show how a new type of pure long range molecular states can allow the resonant magnetic field control of the scattering length. These states arise due to an interplay of an anisotropic (quadrupole) interaction and the magnetic field. Similar anisotropy has been predicted to exist for polar molecule collisions in an electric field [10]. Many-body systems with anistropic interactions might now be explored [11].Trapping of metastable alkaline-earths in magnetooptical [2, 3, 4, 5] and magnetic traps [2,3,4,12] has been demonstrated. A ∼1 s magnetic trap lifetime for densities near 10 10 atoms/cm 3 is observed with metastable 88 Sr in experiments at Rice and Tokyo university [3,13]. These trap lifetimes are limited by background collisions rather than by the radiative lifetime, which is on the order of minutes [1].Molecular potentials -We have calculated short-range adiabatic potentials correlating to two 3 P 2 atoms using a molecular ab initio relativistic valence bond method, as previously described [14]. A variety of attractive and repulsive potentials, and a number of short-range avoided crossings appear among them. Strong collisional loss processes are likely [8] if the atoms approach one another on the a...