Abstract. Ammonium nitrate mixed with aluminum powder forms a non-ideal explosive often referred to as ammonal. Non-ideal detonation can result in significant energy release behind the detonation sonic surface that does not contribute to the detonation velocity, but may affect the expansion energy of the product gases. In this work, we use scaled cylinder expansion tests to characterize the product energy variation with scale for ammonal. The results of two cylinder tests with 50.8-mm and 72.6-mm inner diameters are compared to prior data at other scales. We find that cylinder wall velocity increases with increasing charge diameter and also with increasing charge length.
IntroductionIncreasing charge diameter in a rate-stick experiment (unconfined, cylindrical explosive charge) or cylinder test has a positive effect on detonation velocity, both for ideal and non-ideal explosives. This well-known phenomenon is referred to as the diameter effect. Non-ideal explosives are much more sensitive to confinement and diameter effects, exhibiting increased detonation velocity and confiner-acceleration performance with increased charge diameter and confinement [1][2][3]. This difference in behavior is due to the fact that ideal explosives react promptly, releasing more energy before the sonic surface, while the slower reactions in non-ideal explosives may continue behind the sonic surface. The rate of these post-detonation reactions is likely dependent on temperature, so the higher temperatures associated with larger diameters may result in higher energy release. In the present work, we examine this phenomenon in ammonal cylinder tests.The cylinder test is a standard explosive performance test in which the ability of the explosive to perform work on the confiner material is measured. In the test, explosive is placed inside a confiner tube, which is typically composed of annealed OFHC copper. The test is instrumented to measure the detonation velocity and the position or velocity of the confiner outer wall as a function of time. The detonation front-shape may also be measured with high speed imaging.Commonly used performance metrics derived from the Cylinder test are the Cylinder Energy and the Gurney Energy. The Cylinder Energy includes just the kinetic energy of the confiner, whereas the Gurney Energy is a measure of the product energy available to drive the confiner [4]. In the present work, we report cylinder-wall velocity-profile fit parameters for ammonal composed of 90% ammonium nitrate and 10% aluminum powder, by mass. We also report the