Saturation molalities and standard molar enthalpies of solution of cytidine(cr), hypoxanthine(cr), thymidine(cr), thymine(cr), uridine(cr), and xanthine(cr) in H2O(l)

Tewari, Yadu B.; Gery, Patrick D.; Vaudin, Mark D.; Mighell, A. D.; Klein, Ralph; Goldberg, Robert N.

doi:10.1016/j.jct.2004.04.005

Cited by 16 publications

(13 citation statements)

References 48 publications

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“…1 The purities of the samples were assessed by using high-performance liquid-chromatography (h.p.l.c.) [2]. All of these substances were used as received from the vendor (Sigma) with the exception of 2 0 -deoxycytidine(cr).…”

Section: Methodsmentioning

confidence: 99%

“…The main-period and after-period typically took a combined total of (30 to 40) min. The chromatographic procedures were those used in reference [2]. Typical chromatographic retention times were: 2 0 -deoxyadenosine, 5.4 min; 2 0 -deoxycytidine, 3.4 min; 2 0 -deoxyguanosine, 7.1 min; 2 0 -deoxyinosine, 7.1 min; and 2 0 -deoxyuridine, 5.4 min.…”

Section: Calorimetry Chromatography Saturation Molality Measurementmentioning

confidence: 99%

“…The calculation of standard state quantities has been previously described [2]. Throughout this study, the standard state for the solute is the hypothetical ideal solution of unit molality (m = 1 mol AE kg À1 ).…”

Section: Standard State Quantitiesmentioning

confidence: 99%

“…Where necessary, we have estimated values of pK and D r H m based on chemical similarity with other substances. Thus, the estimated pK and D r H m values for 2 0 -deoxyadenosine, 2 0 -deoxycytidine, 2 0 -deoxyguanosine, 2 0 -deoxyinosine, and 2 0 -deoxyuridine are based, respectively, on the known values of these quantities for adenosine, cytidine, guanosine, inosine, and uridine [2,12]. The pK values given in table 5 show that the predominant species present at the pHs used in the study are uncharged.…”

Section: Standard State Quantitiesmentioning

confidence: 99%

“…In previous investigations [1,2], results for the thermodynamics of the dissolution reactions of several key nucleosides were reported. In this study, we continue our studies of key biochemical substances and report results of measurements of the saturation molalities and molar enthalpies of solution in H 2 O(l) of the biochemical substances 2 0 -deoxyadenosine, 2 0 -deoxycytidine, 2 0 -deoxyguanosine, 2 0 -deoxyinosine, and 2 0 -deoxyuridine (see figure 1).…”

Section: Introductionmentioning

confidence: 99%

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Saturation molalities and standard molar enthalpies of solution of 2′-deoxyadenosine·H2O(cr), 2′-deoxycytidine·H2O(cr), 2′-deoxyguanosine·H2O(cr), 2′-deoxyinosine(cr), and 2′-deoxyuridine(cr) in H2O(l)

Tewari

Gery

Vaudin

et al. 2005

The Journal of Chemical Thermodynamics

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Section: Methodsmentioning

confidence: 99%

Section: Calorimetry Chromatography Saturation Molality Measurementmentioning

confidence: 99%

Section: Standard State Quantitiesmentioning

confidence: 99%

Section: Standard State Quantitiesmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Saturation molalities and standard molar enthalpies of solution of 2′-deoxyadenosine·H2O(cr), 2′-deoxycytidine·H2O(cr), 2′-deoxyguanosine·H2O(cr), 2′-deoxyinosine(cr), and 2′-deoxyuridine(cr) in H2O(l)

Tewari

Gery

Vaudin

et al. 2005

The Journal of Chemical Thermodynamics

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Volumetric Properties of the Nucleosides Adenosine, Cytidine, and Uridine in Aqueous Solution at T = (288.15 and 313.15) K and p = (10 to 100) MPa

2019

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Speeds of sound have been measured for aqueous solutions of the nucleosides adenosine, cytidine, and uridine at the temperatures T = (288.15 and 313.15) K and at the pressures p = (10, 20, 40, 60, 80, and 100) MPa. Using the methods described in our previous work, the partial molar volumes at infinite dilution, V2 o Keywords Speed of sound · Partial molar volume · Partial molar isothermal compression · High pressure · Nucleosides · Aqueous solution

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Interactions of xanthine and its derivatives with cyclodextrins in aqueous solutions

Терехова

2010

Russ Chem Bull

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Using calorimetry, 1 H NMR, UV spectroscopy, and solubility methods, the interactions of natural and hydroxypropylated α , β , and γ cyclodextrins with xanthine and its methylated derivatives (theophylline, theobromine, and caffeine) were studied in aqueous solutions at 298.15 K. Cyclodextrins revealed low complexation ability toward xanthine and its methylated derivatives. Hydroxypropyl γ cyclodextrin with the largest internal cavity is the most effective solubilizing agent for this type of compounds. The calculated thermodynamic parameters are discussed in terms of structural effects of cyclodextrins and purine alkaloids on the character of their intermolecular interactions in aqueous medium.

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Saturation molalities and standard molar enthalpies of solution of cytidine(cr), hypoxanthine(cr), thymidine(cr), thymine(cr), uridine(cr), and xanthine(cr) in H2O(l)

Cited by 16 publications

References 48 publications

Saturation molalities and standard molar enthalpies of solution of 2′-deoxyadenosine·H2O(cr), 2′-deoxycytidine·H2O(cr), 2′-deoxyguanosine·H2O(cr), 2′-deoxyinosine(cr), and 2′-deoxyuridine(cr) in H2O(l)

Saturation molalities and standard molar enthalpies of solution of 2′-deoxyadenosine·H2O(cr), 2′-deoxycytidine·H2O(cr), 2′-deoxyguanosine·H2O(cr), 2′-deoxyinosine(cr), and 2′-deoxyuridine(cr) in H2O(l)

Volumetric Properties of the Nucleosides Adenosine, Cytidine, and Uridine in Aqueous Solution at T = (288.15 and 313.15) K and p = (10 to 100) MPa

Interactions of xanthine and its derivatives with cyclodextrins in aqueous solutions

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