Sandwich structured aryl-diimine Pd (II)/Co (II) monolayer—Fabrication, catalytic performance, synergistic effect and mechanism investigation

Controllable Cyclopalladated Polythiophene Imine Monolayer by Self-Assembly, Hybrid Doping and Electrochemical Polymerization: A Simple Way to Enhance Activity and Stability

“…Comparisons of the reported similar studies are presented in Table S5, indicating that a higher TON value of this work could be obtained. Recycling ability is considered an important factorbecause the recycling and stability of catalysts play an important role in industrial applications [13,[28][29][30][31]. As shown in Figure 7, recycling of these catalytic monolayers is also investigated.…”

Pd/Co3O4–Pd/PdO formed in situ on the surface of the self-assembly ferrocenylimine Pd(ii)/Co(ii) monolayer for catalyzing the Suzuki cross-coupling reaction—formation, synergistic effect, and catalytic mechanism

“…57–62 Previous studies on ligands, the molecular structure of the surface, metal combination, and carrier with the synergy between metals to develop the higher active catalysts have been our effort directions. 14,60–79…”

Pd/Cu2O/CuO as Active Sites on the Cyclometalated Pd(II)/Cu(II) Nanosheet: Active Centre Formation, Synergistic and Catalytic Mechanism

“…There are difficulties for developing and designing efficient multi‐metallic catalysts, such as the preparation method, each component assembling, electronic effects controlling, active center distribution, which must be overcome [28] . Self‐assembly way is usually used to construct structure desired, offering controllable orientation, thickness and stable films [12,17,29–47] . Meanwhile, appropriate supports improving dispersion and utilizing have been intensely investigated for improving the catalytic activity, [48–50] in which the graphene oxide (GO) was recognized as an ideal one because of its physical properties, such as high stability, large surface area, unique 2D [51] .…”

“…[28] Self-assembly way is usually used to construct structure desired, offering controllable orientation, thickness and stable films. [12,17,[29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45][46][47] Meanwhile, appropriate supports improving dispersion and utilizing have been intensely investigated for improving the catalytic activity, [48][49][50] in which the graphene oxide (GO) was recognized as an ideal one because of its physical properties, such as high stability, large surface area, unique 2D. [51] Ligand design and selection are also an integral part in catalyst, [52] in which a privileged Schiff-base ligand can coordinate with various metals and control metal performance during the catalytic transformations.…”