Evaluation of (BH)max and magnetic anisotropy of cobalt ferrite nanoparticles synthesized in gelatin, Ceramics International, http://dx.
AbstractCoFe 2 O 4 nanoparticles were synthesized using gelatin as a polymerizing agent. Structural, morphological and magnetic properties of samples treated at different temperatures were investigated by X-ray diffraction, scanning electron microscopy, Mössbauer spectroscopy and magnetization measurements. Our results revealed that the samples annealed at 623 K and temperatures above 973 K have a cation distributions given by (Co 0.19 Fe 0.81 )[Co 0.81 Fe 1.19 ]O 4 and (Co 0.06 Fe 0.94 )[Co 0.94 Fe 1.06 ]O 4 ,respectively. The particle sizes varied from 73 to 296 nm and the magnetocrystalline anisotropy, K 1 , has values ranging from 2.60x10 6 to 2.71x10 6 J/m 3 , as determined from the law of approach to saturation applied to the MxH data at high field. At 5 K, the saturation magnetization, coercive field and (BH) max varied from 76 to 95 Am 2 /kg, 479.9 to 278.5 kA/m and 9.7 to 20.9 kJ/m 3 , respectively. The reported values are in good agreement with near-stoichiometric cobalt ferrite samples.