Ruthenium nitrosyl complexes [RuNOL2(NO2)2OH] with ethyl isonicotinate and pyrazine: Synthesis, structure and formation of metastable linkage isomers

Solution and solid-state light-induced transformations in heterometallic vanadium-ruthenium nitrosyl complex

“…The population of MS1 is about 5%. The band exhibits a shift to lower energies compared to the GS band by 150 cm -1 , which is characteristic for nitrosyl ruthenium complexes [2,12,71,[95][96][97]. The concomitant decrease of intensities of the NO 2 bands is most probably related to the nitrosyl isomerization and partial NO release (see below) (Fig.…”

Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide

“…22 For the construction of a RuNO-containing linker, ethyl isonicotinate (inicEt) is preferable compared to isonicotinic acid itself due to better solubility and selectivity of ruthenium coordination. In the case of octahedral coordination of the metal center, cis - and trans -coordinations of ethyl isonicotinates are possible; 23 however, we focused on the trans -isomer which better mimics popular terephthalate. 24…”

Synthesis of the Ruthenium Nitrosyl Complex with Coordinated Ammonia and Pyridine at Room Temperature

“…The pyridine ruthenium complexes containing nitrosyl group are known . It is worth mentioning that the synthetic methods for pyridine complexes can be adjusted to obtain complexes with pyridine‐like ligands , . Therefore, the design of the desired complexes are straightforward once the synthetic routes of the pyridine analogs are established.…”