2017
DOI: 10.1039/c7cc07777g
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Ruthenium-catalyzed olefinic C–H alkenylation of enol-carbamates: highly stereo-selective synthesis of (Z,Z) and (Z,E)-butadienes

Abstract: Cross-coupling reactions of enol carbamates with alkynes or alkenes are reported, using an inexpensive ruthenium catalyst. With the assistance of the directing group OCONMe, the protocols provide mild, stereo-selective and efficient routes for the preparation of valuable (Z,Z) and (Z,E)-butadiene skeletons.

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Cited by 57 publications
(40 citation statements)
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“…Looking for a higher efficiency of the FRET process, and thus a higher sensitivity of the method, Liu et al proposed the use of graphene oxide (GO) as efficient acceptor, since it quenches totally the visible emissions of the RE-NPs due to their ultrahighly strong absorption [81]. After quenching the emission from singlestranded DNA-functionalized Er 3+ , Yb 3+ -doped NaYF4 NPs by their adsorption on the surface of GO their fluorescence can be recovered by addition of adenosine triphosphate (ATP) ( Figure 5).…”
Section: Sensing and Analytical Applicationsmentioning
confidence: 99%
“…Looking for a higher efficiency of the FRET process, and thus a higher sensitivity of the method, Liu et al proposed the use of graphene oxide (GO) as efficient acceptor, since it quenches totally the visible emissions of the RE-NPs due to their ultrahighly strong absorption [81]. After quenching the emission from singlestranded DNA-functionalized Er 3+ , Yb 3+ -doped NaYF4 NPs by their adsorption on the surface of GO their fluorescence can be recovered by addition of adenosine triphosphate (ATP) ( Figure 5).…”
Section: Sensing and Analytical Applicationsmentioning
confidence: 99%
“…The C‐PDA was fabricated using a Friedel–Crafts hyper‐cross‐linking . 5 g p ‐phenylenediamine, 70 mL 1, 2‐dichloroethane, and 10 mL dimethoxymethane were added in a three‐neck flask under room temperature with a magnetic stirring.…”
Section: Methodsmentioning
confidence: 99%
“…In photocatalytic degradation of organic molecules, . OH and . O 2 −[68,75] radicals are believed as the key active species (the example detail discussion could refer to Entry 13, 16 and 27).…”
Section: Photobiorefinery Routes For Chemical Productionmentioning
confidence: 99%