Ruthenium-catalysed formylation of amines with dense carbon dioxide as C1-source

Schmid, Lorenz; Canonica, Adrian; Baiker, Alfons

doi:10.1016/s0926-860x(03)00641-0

Cited by 58 publications

(28 citation statements)

References 33 publications

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“…Formylation of various cyclic and aliphatic amines with scCO 2 using the ruthenium catalyst RuCl 2 (dppe) 2 affords almost 100% selectivity. 314,315 A complex phase behavior of the reaction mixture was observed during the reaction, including formation of solid carbamate. Addition of water to the reaction mixture suppresses formation of the carbamate and enhances the rate of reaction.…”

Section: Synthesis Of Formamidesmentioning

confidence: 99%

Recent advances in catalytic hydrogenation of carbon dioxide

et al. 2011

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Owing to the increasing emissions of carbon dioxide (CO 2 ), human life and the ecological environment have been affected by global warming and climate changes. To mitigate the concentration of CO 2 in the atmosphere various strategies have been implemented such as separation, storage, and utilization of CO 2 . Although it has been explored for many years, hydrogenation reaction, an important representative among chemical conversions of CO 2 , offers challenging opportunities for sustainable development in energy and the environment. Indeed, the hydrogenation of CO 2 not only reduces the increasing CO 2 buildup but also produces fuels and chemicals. In this critical review we discuss recent developments in this area, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism. We also provide an overview regarding the challenges and opportunities for future research in the field (319 references).

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Section: Synthesis Of Formamidesmentioning

confidence: 99%

Recent advances in catalytic hydrogenation of carbon dioxide

et al. 2011

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“…The undivided electrolysis cell was connected to a 6 V battery and was used to demonstrate the conversion of aliphatic and aromatic aldehydes to the corresponding alcohols. heat, hydrazones can decompose to form the corresponding alkyls (82). The overall reaction sequence is known as the Wolff-Kishner reaction (Scheme 14).…”

Section: Electrochemical Reduction On Cu Electrodesmentioning

confidence: 99%

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2 – The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates

Luca

Fenwick

2015

Journal of Photochemistry and Photobiology B: Biology

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Available online xxxx a b s t r a c tThe present review covers organic transformations involved in the reduction of CO 2 to chemical fuels. In particular, we focus on reactions of CO 2 with organic molecules to yield carboxylic acid derivatives as a first step in CO 2 reduction reaction sequences. These biomimetic initial steps create opportunities for tandem electrochemical/chemical reductions. We draw parallels between long-standing knowledge of CO 2 reactivity from organic chemistry, organocatalysis, surface science and electrocatalysis. We point out some possible non-faradaic chemical reactions that may contribute to product distributions in the production of solar fuels from CO 2 . These reactions may be accelerated by thermal effects such as resistive heating and illumination.

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“…The formation of carbonyl groups without subsequent hydrogenation of a double bond is possible if the formylation is carried out on an amine [30]. The driving force is still low (D R g IG ≈ +24 to +68 kJ mol -1 ), but for some amines nameable conversions are possible.…”

Section: Formylation Of Aminesmentioning

confidence: 99%

Thermodynamic Constraints for the Utilization of CO₂

Müller

Mokrushina

Arlt

2014

Chemie Ingenieur Technik

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In the present paper the linear quasi static theory of viscoelasticity for Kelvin‐Voigt materials with double porosity is considered. The basic external boundary value problems (BVPs) of steady vibrations in this theory are formulated. The uniqueness and existence theorems for regular (classical) solutions of the BVPs are proved by using of the potential method (boundary integral equations method) and the theory of singular integral equations. (© 2016 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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Ruthenium-catalysed formylation of amines with dense carbon dioxide as C1-source

Cited by 58 publications

References 33 publications

Recent advances in catalytic hydrogenation of carbon dioxide

Recent advances in catalytic hydrogenation of carbon dioxide

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2 – The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates

Thermodynamic Constraints for the Utilization of CO₂

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Ruthenium-catalysed formylation of amines with dense carbon dioxide as C1-source

Cited by 58 publications

References 33 publications

Recent advances in catalytic hydrogenation of carbon dioxide

Recent advances in catalytic hydrogenation of carbon dioxide

Organic reactions for the electrochemical and photochemical production of chemical fuels from CO2 – The reduction chemistry of carboxylic acids and derivatives as bent CO2 surrogates

Thermodynamic Constraints for the Utilization of CO2

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Thermodynamic Constraints for the Utilization of CO₂