RUB-23: a new microporous lithosilicate containing spiro-5 building units

Park, Sohyun H; Daniels, Peter J. L.; Gies, Hermann

doi:10.1016/s1387-1811(99)00260-7

Cited by 50 publications

(33 citation statements)

References 20 publications

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“…Since only one reported nanoporous aluminosilicate has 3-rings (27), the search for tetrahedrally connected open frameworks containing 3-rings has expanded to other systems, including the beryllo-(28, 29), litho- (30), and zincosilicates (31}33); beryllo-(34) and zincophosphates (35); and alumino-and gallogermanates (36 (27, 29, 30, 32}34).…”

Section: Discussionmentioning

confidence: 99%

Synthesis and Structures of a Layered and a Tubular Antimony(III) Phosphonate

Adair¹,

Guillou²,

Alvarez³

et al. 2001

Journal of Solid State Chemistry

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Section: Discussionmentioning

confidence: 99%

Synthesis and Structures of a Layered and a Tubular Antimony(III) Phosphonate

Adair¹,

Guillou²,

Alvarez³

et al. 2001

Journal of Solid State Chemistry

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“…103 Recently, a porous lithiosilicate (RUB-23) has been synthesized, where the Li + is in 3-MRs. 103 The framework density of RUB-23 is high (17.7) and the thermal stability is low. However, RUB-23 proves that structures containing 3-MRs can be prepared with Li + .…”

Section: T Atomsmentioning

confidence: 99%

Assembly of Zeolites and Crystalline Molecular Sieves

Anthony

Davis

Nanostructure Science and Technology

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“…6.18 , right). Representative materials are RUB-23 [ 145 ], RUB-29 [ 146 ], and RUB-12 [ 147 ]. Apart from these examples of T atoms in spiro-5 units in silicates, there are in all 23 type materials listed in the zeolite framework data base [ 148 ] with spiro-5 units in aluminosilicate, germanate, phosphate, arsenate, etc., microporous frameworks.…”

Section: Three Rings and Spiro-5 Unitsmentioning

confidence: 99%

Structure Analysis in Zeolite Research: From Framework Topologies to Functional Properties

Gies

Marler

2016

Green Chemistry and Sustainable Technology

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The solution and the refi nement of crystal structures of microporous materials are of prime interest for the synthesis and application community in porous solid research. The structure of a material reveals not only the geometry of the bonding network of the rigid framework but also the location of the nonframework constituents responsible for the porosity of the material. Analyzing the structure, therefore, unveils the synthesis protocol including nucleation and growth. The properties related to the porous net correspond to the local structure, i.e., the composition and the geometry of local confi gurations. It thus inspires ideas about possible properties and modifi cations to improve functionality.The chapter is intended to highlight the contribution of crystallographic analysis of microporous materials and in particular porous silicates to the success of this class of materials. It does not survey the continuous growth of materials in the fi eld but show how the insight gained from crystallographic studies acted as catalyst in the further development of the fi eld.

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RUB-23: a new microporous lithosilicate containing spiro-5 building units

Cited by 50 publications

References 20 publications

Synthesis and Structures of a Layered and a Tubular Antimony(III) Phosphonate

Synthesis and Structures of a Layered and a Tubular Antimony(III) Phosphonate

Assembly of Zeolites and Crystalline Molecular Sieves

Structure Analysis in Zeolite Research: From Framework Topologies to Functional Properties

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