“…Eqs. (1) and (2) show that the interdiffusion coefficient D ML can be smaller than D o if k/f 00 < 0 or larger than D o if k/f 00 > 0, respectively. For binary systems with negative heat of mixing like CuePd, CueAu, CoePt etc, k/f 00 is less than zero, because f 00 > 0 and k < 0 [44e46].…”