Ru(II) and Ru(III) complexes containing N‐acylthiourea ligands: Supramolecular structures and synthons, reduction, and reaction pathway of aromatic nitro compounds
Abstract:Four ruthenium complexes {[RuCl(CO)(PPh 3 ) 2 L 1 ], [RuCl(CO)(PPh 3 ) 2 L 2 ],[RuCl 2 (PPh 3 ) 2 L 1 ] and [RuCl 2 (PPh 3 ) 2 L 2 ]} supported with N-acylthiourea-based ligands were synthesized. The compounds prepared were characterized by 1 H NMR, 13 C NMR, elemental analysis, UV-vis, and magnetic susceptibility methods. The characterization of the molecular structure of two ruthenium complexes {[RuCl(CO)(PPh 3 ) 2 L 1 ] and [RuCl 2 (PPh 3 ) 2 L 1 ]} was also performed using the single crystal X-ray diffract… Show more
This literature update is a continuation of our efforts to compile comprehensive data on research endeavors concerning acyl thioureas over the past two years.
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