As a method to maximize the energy efficiency of triboelectric nanogenerators (TENGs), highâvoltage charge injection (HVCI) on the surface is a simple and effective method for increasing surface charge densities. In this study, positive and negative triboelectric series are controlled using a 3âlayer gradient chargeâconfinement wherein the particle sizes of the mesoporous carbon spheres (mCSs) are sequentially arranged depending on the external surface area of the mCSs. In the gradient chargeâconfinement layers of this study, the mCS with different sizes perform charge transport from the surface to a deep position during HVCI while mitigating the charge loss through charge confinement to induce the high space charge densities. Through this process, the output voltageâwhich is initially 15.2 Vâis measured to be 600 V after HVCI, thus representing an increase of about 40 times. Further, to amplify the low output current, which is a disadvantage of triboelectric energy, two types of electrical energyâtriboelectric and electromagnetic energyâare produced in single mechanical motion. As a result, the output current produced by the cylindrical TENG and electromagnetic generator is recorded as being 1300 times higher, increasing from 12.8 ”A to 17.5 mA.