“…Another local mode analysis of the vibrational energies of stibine was carried out by means of the creation and annihilation operators technique [41,42]. Ab initio studies [26,27] were performed to calculate the PES, the dipole moments, the equilibrium geometries, and effective rotation-vibration constants for 121 SbH 3 and 123 SbH 3 , and 123 SbD 3 . Pluchart et al [43] used their algebraic approach to describe vibrational modes of SbH 3 .…”