The electronic and photoluminescence (PL) properties of a-Si(Er):H films prepared by metalorganic (Er(HFA) 3 *DME) assisted PECVD with strongly hydrogen-diluted silane (2% SiH 4 in H 2 ) at T S = 250 • C are discussed. The conductivity (10 −9 −10 −2 −1 cm −1 within the range of 140-385 K), Tauc optical gap (1.8-2.1 eV), Raman and IR optical spectra, and the wavelength of erbium-related PL correlate with the amount of Er(HFA) 3 *DME compound sublimed during the deposition process.